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Toward Asymmetric Synthesis of Pentaorganosilicates

Introducing chiral silicon centers was explored for the asymmetric Rh-catalyzed cyclization of dihydrosilanes to enantiomerically enriched spirosilanes as targets to enable access to enantiostable pentacoordinate silicates. The steric rigidity required in such systems demands the presence of two nap...

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Detalles Bibliográficos
Autores principales:	van der Boon, Leon J. P., Fuku-en, Shin-ichi, Slootweg, J. Chris, Lammertsma, Koop, Ehlers, Andreas W.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Springer US 2018
Materias:	Original Paper
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6445452/ https://www.ncbi.nlm.nih.gov/pubmed/31007498 http://dx.doi.org/10.1007/s11244-018-0967-5

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