Key Mechanistic Features in Palladium-Catalyzed Methylcyclopropanation of Norbornenes With Vinyl Bromides: Insights From DFT Calculations

DFT calculations were performed to elucidate mechanistic details of an unusual palladium-catalyzed methylcyclopropanation from [2 + 1] cycloadditions of (Z)-2-bromovinylbenzene and endo-N-(p-tolyl)-norbornenesuccinimide. The reaction proceeds via oxidative addition (OA), intermolecular alkene insert...

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Detalles Bibliográficos
Autores principales: Ying, Fang, Zhang, Yutong, Xiang, Chuyue, Song, Zhijun, Xie, Hujun, Bao, Weiliang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Frontiers Media S.A. 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6445852/
https://www.ncbi.nlm.nih.gov/pubmed/30972329
http://dx.doi.org/10.3389/fchem.2019.00169

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