Alkene hydrosilylation catalyzed by easily assembled Ni(ii)-carboxylate MOFs

We report the first Ni MOF catalysts for anti-Markovnikov hydrosilylation of alkenes. These catalysts are bench-stable and easily-assembled from simple Ni salts and carboxylic acids. The best catalyst gives turnover numbers up to 9500 and is robust even after 10 recycling runs. The catalyst can be a...

Descripción completa

Detalles Bibliográficos
Autores principales: Zhang, Zhikun, Bai, Lichen, Hu, Xile
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6446965/
https://www.ncbi.nlm.nih.gov/pubmed/30996968
http://dx.doi.org/10.1039/c9sc00126c
_version_ 1783408445053992960
author Zhang, Zhikun
Bai, Lichen
Hu, Xile
author_facet Zhang, Zhikun
Bai, Lichen
Hu, Xile
author_sort Zhang, Zhikun
collection PubMed
description We report the first Ni MOF catalysts for anti-Markovnikov hydrosilylation of alkenes. These catalysts are bench-stable and easily-assembled from simple Ni salts and carboxylic acids. The best catalyst gives turnover numbers up to 9500 and is robust even after 10 recycling runs. The catalyst can be applied for the hydrosilylation of a wide range of alkenes, achieving good synthetic utility and functional group tolerance.
format Online
Article
Text
id pubmed-6446965
institution National Center for Biotechnology Information
language English
publishDate 2019
publisher Royal Society of Chemistry
record_format MEDLINE/PubMed
spelling pubmed-64469652019-04-17 Alkene hydrosilylation catalyzed by easily assembled Ni(ii)-carboxylate MOFs Zhang, Zhikun Bai, Lichen Hu, Xile Chem Sci Chemistry We report the first Ni MOF catalysts for anti-Markovnikov hydrosilylation of alkenes. These catalysts are bench-stable and easily-assembled from simple Ni salts and carboxylic acids. The best catalyst gives turnover numbers up to 9500 and is robust even after 10 recycling runs. The catalyst can be applied for the hydrosilylation of a wide range of alkenes, achieving good synthetic utility and functional group tolerance. Royal Society of Chemistry 2019-02-25 /pmc/articles/PMC6446965/ /pubmed/30996968 http://dx.doi.org/10.1039/c9sc00126c Text en This journal is © The Royal Society of Chemistry 2019 http://creativecommons.org/licenses/by/3.0/ This article is freely available. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence (CC BY 3.0)
spellingShingle Chemistry
Zhang, Zhikun
Bai, Lichen
Hu, Xile
Alkene hydrosilylation catalyzed by easily assembled Ni(ii)-carboxylate MOFs
title Alkene hydrosilylation catalyzed by easily assembled Ni(ii)-carboxylate MOFs
title_full Alkene hydrosilylation catalyzed by easily assembled Ni(ii)-carboxylate MOFs
title_fullStr Alkene hydrosilylation catalyzed by easily assembled Ni(ii)-carboxylate MOFs
title_full_unstemmed Alkene hydrosilylation catalyzed by easily assembled Ni(ii)-carboxylate MOFs
title_short Alkene hydrosilylation catalyzed by easily assembled Ni(ii)-carboxylate MOFs
title_sort alkene hydrosilylation catalyzed by easily assembled ni(ii)-carboxylate mofs
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6446965/
https://www.ncbi.nlm.nih.gov/pubmed/30996968
http://dx.doi.org/10.1039/c9sc00126c
work_keys_str_mv AT zhangzhikun alkenehydrosilylationcatalyzedbyeasilyassembledniiicarboxylatemofs
AT bailichen alkenehydrosilylationcatalyzedbyeasilyassembledniiicarboxylatemofs
AT huxile alkenehydrosilylationcatalyzedbyeasilyassembledniiicarboxylatemofs

Ejemplares similares