Methane Cracking over Cobalt Molybdenum Carbides

ABSTRACT: The catalytic behaviour of Co(3)Mo(3)C, Co(6)Mo(6)C, Co(3)Mo(3)N and Co(6)Mo(6)N for methane cracking has been studied to determine the relationship between the methane cracking activity and the chemical composition. The characterisation of post-reaction samples showed a complex phase comp...

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Detalles Bibliográficos
Autores principales: Alshibane, I., Laassiri, S., Rico, J. L., Hargreaves, J. S. J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Springer US 2018
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6448361/
https://www.ncbi.nlm.nih.gov/pubmed/31007483
http://dx.doi.org/10.1007/s10562-018-2378-4
Descripción
Sumario:ABSTRACT: The catalytic behaviour of Co(3)Mo(3)C, Co(6)Mo(6)C, Co(3)Mo(3)N and Co(6)Mo(6)N for methane cracking has been studied to determine the relationship between the methane cracking activity and the chemical composition. The characterisation of post-reaction samples showed a complex phase composition with the presence of Co(3)Mo(3)C, α-Co and β-Mo(2)C as catalytic phases and the deposition of different forms of carbon during reaction. GRAPHICAL ABSTRACT: [Image: see text] ELECTRONIC SUPPLEMENTARY MATERIAL: The online version of this article (10.1007/s10562-018-2378-4) contains supplementary material, which is available to authorized users.

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