Methane Cracking over Cobalt Molybdenum Carbides

ABSTRACT: The catalytic behaviour of Co(3)Mo(3)C, Co(6)Mo(6)C, Co(3)Mo(3)N and Co(6)Mo(6)N for methane cracking has been studied to determine the relationship between the methane cracking activity and the chemical composition. The characterisation of post-reaction samples showed a complex phase comp...

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Autores principales: Alshibane, I., Laassiri, S., Rico, J. L., Hargreaves, J. S. J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Springer US 2018
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6448361/
https://www.ncbi.nlm.nih.gov/pubmed/31007483
http://dx.doi.org/10.1007/s10562-018-2378-4
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author Alshibane, I.
Laassiri, S.
Rico, J. L.
Hargreaves, J. S. J.
author_facet Alshibane, I.
Laassiri, S.
Rico, J. L.
Hargreaves, J. S. J.
author_sort Alshibane, I.
collection PubMed
description ABSTRACT: The catalytic behaviour of Co(3)Mo(3)C, Co(6)Mo(6)C, Co(3)Mo(3)N and Co(6)Mo(6)N for methane cracking has been studied to determine the relationship between the methane cracking activity and the chemical composition. The characterisation of post-reaction samples showed a complex phase composition with the presence of Co(3)Mo(3)C, α-Co and β-Mo(2)C as catalytic phases and the deposition of different forms of carbon during reaction. GRAPHICAL ABSTRACT: [Image: see text] ELECTRONIC SUPPLEMENTARY MATERIAL: The online version of this article (10.1007/s10562-018-2378-4) contains supplementary material, which is available to authorized users.
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spelling pubmed-64483612019-04-17 Methane Cracking over Cobalt Molybdenum Carbides Alshibane, I. Laassiri, S. Rico, J. L. Hargreaves, J. S. J. Catal Letters Article ABSTRACT: The catalytic behaviour of Co(3)Mo(3)C, Co(6)Mo(6)C, Co(3)Mo(3)N and Co(6)Mo(6)N for methane cracking has been studied to determine the relationship between the methane cracking activity and the chemical composition. The characterisation of post-reaction samples showed a complex phase composition with the presence of Co(3)Mo(3)C, α-Co and β-Mo(2)C as catalytic phases and the deposition of different forms of carbon during reaction. GRAPHICAL ABSTRACT: [Image: see text] ELECTRONIC SUPPLEMENTARY MATERIAL: The online version of this article (10.1007/s10562-018-2378-4) contains supplementary material, which is available to authorized users. Springer US 2018-04-21 2018 /pmc/articles/PMC6448361/ /pubmed/31007483 http://dx.doi.org/10.1007/s10562-018-2378-4 Text en © The Author(s) 2018 Open AccessThis article is distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution, and reproduction in any medium, provided you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made.
spellingShingle Article
Alshibane, I.
Laassiri, S.
Rico, J. L.
Hargreaves, J. S. J.
Methane Cracking over Cobalt Molybdenum Carbides
title Methane Cracking over Cobalt Molybdenum Carbides
title_full Methane Cracking over Cobalt Molybdenum Carbides
title_fullStr Methane Cracking over Cobalt Molybdenum Carbides
title_full_unstemmed Methane Cracking over Cobalt Molybdenum Carbides
title_short Methane Cracking over Cobalt Molybdenum Carbides
title_sort methane cracking over cobalt molybdenum carbides
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6448361/
https://www.ncbi.nlm.nih.gov/pubmed/31007483
http://dx.doi.org/10.1007/s10562-018-2378-4
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AT laassiris methanecrackingovercobaltmolybdenumcarbides
AT ricojl methanecrackingovercobaltmolybdenumcarbides
AT hargreavesjsj methanecrackingovercobaltmolybdenumcarbides

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