Cargando…
Manganese-Catalyzed α-Alkylation of Ketones, Esters, and Amides Using Alcohols
[Image: see text] Herein we report the manganese-catalyzed C–C bond-forming reactions via α-alkylation of ketones, amides, and esters, using primary alcohols. β-Alkylation of secondary alcohols by primary alcohols to obtain α-alkylated ketones is also reported. The reactions are catalyzed by a ((i)P...
Autores principales: | Chakraborty, Subrata, Daw, Prosenjit, Ben David, Yehoshoa, Milstein, David |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American
Chemical Society
2018
|
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6466737/ https://www.ncbi.nlm.nih.gov/pubmed/31007965 http://dx.doi.org/10.1021/acscatal.8b03720 |
Ejemplares similares
-
Acceptorless
Dehydrogenative Coupling Using Ammonia:
Direct Synthesis of N-Heteroaromatics from Diols Catalyzed
by Ruthenium
por: Daw, Prosenjit, et al.
Publicado: (2018) -
Highly Selective, Efficient Deoxygenative Hydrogenation
of Amides Catalyzed by a Manganese Pincer Complex via Metal–Ligand Cooperation
por: Zou, You-Quan, et al.
Publicado: (2018) -
Synthesis of Pyrazines and Quinoxalines via Acceptorless
Dehydrogenative Coupling Routes Catalyzed by Manganese Pincer Complexes
por: Daw, Prosenjit, et al.
Publicado: (2018) -
Manganese-Pincer-Catalyzed Nitrile Hydration, α-Deuteration,
and α-Deuterated
Amide Formation via Metal Ligand Cooperation
por: Zhou, Quan-Quan, et al.
Publicado: (2021) -
Selective Room-Temperature Hydrogenation of Amides to Amines and Alcohols Catalyzed
by a Ruthenium Pincer Complex and Mechanistic Insight
por: Kar, Sayan, et al.
Publicado: (2020)