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3D-Printed Polyester-Based Prototypes for Cosmetic Applications—Future Directions at the Forensic Engineering of Advanced Polymeric Materials

Knowledge of degradation and impairment phenomena of (bio)degradable polymeric materials under operating conditions, and thus the selection of test procedures and prediction of their behavior designates the scope and capabilities as well as possible limitations of both: the preparation of the final...

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Autores principales: Rydz, Joanna, Sikorska, Wanda, Musioł, Marta, Janeczek, Henryk, Włodarczyk, Jakub, Misiurska-Marczak, Marlena, Łęczycka, Justyna, Kowalczuk, Marek
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6470545/
https://www.ncbi.nlm.nih.gov/pubmed/30917574
http://dx.doi.org/10.3390/ma12060994
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author Rydz, Joanna
Sikorska, Wanda
Musioł, Marta
Janeczek, Henryk
Włodarczyk, Jakub
Misiurska-Marczak, Marlena
Łęczycka, Justyna
Kowalczuk, Marek
author_facet Rydz, Joanna
Sikorska, Wanda
Musioł, Marta
Janeczek, Henryk
Włodarczyk, Jakub
Misiurska-Marczak, Marlena
Łęczycka, Justyna
Kowalczuk, Marek
author_sort Rydz, Joanna
collection PubMed
description Knowledge of degradation and impairment phenomena of (bio)degradable polymeric materials under operating conditions, and thus the selection of test procedures and prediction of their behavior designates the scope and capabilities as well as possible limitations of both: the preparation of the final product and its durability. The main novelty and objective of this research was to determine the degradation pathways during testing of polylactide and polylactide/polyhydroxyalkanoate materials made with three-dimensional printing and the development of a new strategy for the comprehensive characterization of such complex systems including behavior during waste disposal. Prototype objects were subjected to tests for damage evolution performed under simulating operating conditions. The reference samples and the tested items were characterized by gel permeation chromatography and differential scanning calorimetry to determine changes in material properties. The studies showed that: polyhydroxyalkanoate component during accelerated aging and degradation in environments rich in microorganisms accelerated the degradation of the material; paraffin accelerates polylactide degradation and slows degradation of polyhydroxyalkanoate-based material; under the influence of an environment rich in enzymes, paraffin contamination accelerates biodegradation; under the influence of natural conditions, paraffin contamination slowed degradation; the processing conditions, in particular the printing orientation of individual parts of the container, influenced the material properties in its various regions, affecting the rate of degradation of individual parts.
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spelling pubmed-64705452019-04-27 3D-Printed Polyester-Based Prototypes for Cosmetic Applications—Future Directions at the Forensic Engineering of Advanced Polymeric Materials Rydz, Joanna Sikorska, Wanda Musioł, Marta Janeczek, Henryk Włodarczyk, Jakub Misiurska-Marczak, Marlena Łęczycka, Justyna Kowalczuk, Marek Materials (Basel) Article Knowledge of degradation and impairment phenomena of (bio)degradable polymeric materials under operating conditions, and thus the selection of test procedures and prediction of their behavior designates the scope and capabilities as well as possible limitations of both: the preparation of the final product and its durability. The main novelty and objective of this research was to determine the degradation pathways during testing of polylactide and polylactide/polyhydroxyalkanoate materials made with three-dimensional printing and the development of a new strategy for the comprehensive characterization of such complex systems including behavior during waste disposal. Prototype objects were subjected to tests for damage evolution performed under simulating operating conditions. The reference samples and the tested items were characterized by gel permeation chromatography and differential scanning calorimetry to determine changes in material properties. The studies showed that: polyhydroxyalkanoate component during accelerated aging and degradation in environments rich in microorganisms accelerated the degradation of the material; paraffin accelerates polylactide degradation and slows degradation of polyhydroxyalkanoate-based material; under the influence of an environment rich in enzymes, paraffin contamination accelerates biodegradation; under the influence of natural conditions, paraffin contamination slowed degradation; the processing conditions, in particular the printing orientation of individual parts of the container, influenced the material properties in its various regions, affecting the rate of degradation of individual parts. MDPI 2019-03-26 /pmc/articles/PMC6470545/ /pubmed/30917574 http://dx.doi.org/10.3390/ma12060994 Text en © 2019 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Rydz, Joanna
Sikorska, Wanda
Musioł, Marta
Janeczek, Henryk
Włodarczyk, Jakub
Misiurska-Marczak, Marlena
Łęczycka, Justyna
Kowalczuk, Marek
3D-Printed Polyester-Based Prototypes for Cosmetic Applications—Future Directions at the Forensic Engineering of Advanced Polymeric Materials
title 3D-Printed Polyester-Based Prototypes for Cosmetic Applications—Future Directions at the Forensic Engineering of Advanced Polymeric Materials
title_full 3D-Printed Polyester-Based Prototypes for Cosmetic Applications—Future Directions at the Forensic Engineering of Advanced Polymeric Materials
title_fullStr 3D-Printed Polyester-Based Prototypes for Cosmetic Applications—Future Directions at the Forensic Engineering of Advanced Polymeric Materials
title_full_unstemmed 3D-Printed Polyester-Based Prototypes for Cosmetic Applications—Future Directions at the Forensic Engineering of Advanced Polymeric Materials
title_short 3D-Printed Polyester-Based Prototypes for Cosmetic Applications—Future Directions at the Forensic Engineering of Advanced Polymeric Materials
title_sort 3d-printed polyester-based prototypes for cosmetic applications—future directions at the forensic engineering of advanced polymeric materials
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6470545/
https://www.ncbi.nlm.nih.gov/pubmed/30917574
http://dx.doi.org/10.3390/ma12060994
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