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Aging Mechanism of a Diatomite-Modified Asphalt Binder Using Fourier-Transform Infrared (FTIR) Spectroscopy Analysis

In this paper, Fourier-transform infrared (FTIR) spectroscopy was used to evaluate the effects of diatomite on aging properties of an asphalt binder. The modified asphalts included 5%, 10%, and 15% diatomite, and were prepared in the laboratory. The changes in functional groups of asphalt were emplo...

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Autores principales: Zhang, Peng, Guo, Qinglin, Tao, Jinglin, Ma, Dehua, Wang, Yedan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6470571/
https://www.ncbi.nlm.nih.gov/pubmed/30917486
http://dx.doi.org/10.3390/ma12060988
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author Zhang, Peng
Guo, Qinglin
Tao, Jinglin
Ma, Dehua
Wang, Yedan
author_facet Zhang, Peng
Guo, Qinglin
Tao, Jinglin
Ma, Dehua
Wang, Yedan
author_sort Zhang, Peng
collection PubMed
description In this paper, Fourier-transform infrared (FTIR) spectroscopy was used to evaluate the effects of diatomite on aging properties of an asphalt binder. The modified asphalts included 5%, 10%, and 15% diatomite, and were prepared in the laboratory. The changes in functional groups of asphalt were employed to investigate the aging mechanisms of the modified and control asphalts. Effects of diatomite on the anti-aging properties of asphalt were analyzed via the changes in intensity of the absorption peaks. Results showed that there were no new functional groups generated after diatomite mixing with asphalt. This indicated that the process of diatomite modification was just physical mixing. Furthermore, parts of saturates and aromatics were volatilized in the aging process of modified asphalt. Polar molecules reacted with oxygen in aging. Meanwhile, carbonyl (C=O) and sulfoxide (S=O) were also generated. The aging resistance of modified asphalt was the best when the diatomite content was 10%. The work of this paper may provide a new perspective to evaluate asphalt aging.
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spelling pubmed-64705712019-04-27 Aging Mechanism of a Diatomite-Modified Asphalt Binder Using Fourier-Transform Infrared (FTIR) Spectroscopy Analysis Zhang, Peng Guo, Qinglin Tao, Jinglin Ma, Dehua Wang, Yedan Materials (Basel) Article In this paper, Fourier-transform infrared (FTIR) spectroscopy was used to evaluate the effects of diatomite on aging properties of an asphalt binder. The modified asphalts included 5%, 10%, and 15% diatomite, and were prepared in the laboratory. The changes in functional groups of asphalt were employed to investigate the aging mechanisms of the modified and control asphalts. Effects of diatomite on the anti-aging properties of asphalt were analyzed via the changes in intensity of the absorption peaks. Results showed that there were no new functional groups generated after diatomite mixing with asphalt. This indicated that the process of diatomite modification was just physical mixing. Furthermore, parts of saturates and aromatics were volatilized in the aging process of modified asphalt. Polar molecules reacted with oxygen in aging. Meanwhile, carbonyl (C=O) and sulfoxide (S=O) were also generated. The aging resistance of modified asphalt was the best when the diatomite content was 10%. The work of this paper may provide a new perspective to evaluate asphalt aging. MDPI 2019-03-26 /pmc/articles/PMC6470571/ /pubmed/30917486 http://dx.doi.org/10.3390/ma12060988 Text en © 2019 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Zhang, Peng
Guo, Qinglin
Tao, Jinglin
Ma, Dehua
Wang, Yedan
Aging Mechanism of a Diatomite-Modified Asphalt Binder Using Fourier-Transform Infrared (FTIR) Spectroscopy Analysis
title Aging Mechanism of a Diatomite-Modified Asphalt Binder Using Fourier-Transform Infrared (FTIR) Spectroscopy Analysis
title_full Aging Mechanism of a Diatomite-Modified Asphalt Binder Using Fourier-Transform Infrared (FTIR) Spectroscopy Analysis
title_fullStr Aging Mechanism of a Diatomite-Modified Asphalt Binder Using Fourier-Transform Infrared (FTIR) Spectroscopy Analysis
title_full_unstemmed Aging Mechanism of a Diatomite-Modified Asphalt Binder Using Fourier-Transform Infrared (FTIR) Spectroscopy Analysis
title_short Aging Mechanism of a Diatomite-Modified Asphalt Binder Using Fourier-Transform Infrared (FTIR) Spectroscopy Analysis
title_sort aging mechanism of a diatomite-modified asphalt binder using fourier-transform infrared (ftir) spectroscopy analysis
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6470571/
https://www.ncbi.nlm.nih.gov/pubmed/30917486
http://dx.doi.org/10.3390/ma12060988
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