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Metal‐Free Radical Borylation of Alkyl and Aryl Iodides

A metal‐free radical borylation of alkyl and aryl iodides with bis(catecholato)diboron (B(2)cat(2)) as the boron source under mild conditions is introduced. The borylation reaction is operationally easy to conduct and shows high functional group tolerance and broad substrate scope. Radical clock exp...

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Detalles Bibliográficos
Autores principales: Cheng, Ying, Mück‐Lichtenfeld, Christian, Studer, Armido
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6470957/
https://www.ncbi.nlm.nih.gov/pubmed/30332527
http://dx.doi.org/10.1002/anie.201810782