Cargando…

An Approach to the Uniform Dispersion of Graphene Nanosheets in Powder Metallurgy Nickel-Based Superalloy

In this paper, a wet-chemical based method was adopted to acquire the uniform dispersion of graphene nanosheets (GNSs) in a powder metallurgy nickel-based superalloy (FGH96) to fabricate a new GNSs reinforced FGH96 metal matrix composite. The surface of the FGH96 powder was modified using a hydrophi...

Descripción completa

Detalles Bibliográficos
Autores principales: Gao, Yu-Xi, Zou, Jin-Wen, Wang, Xiao-Feng, Yang, Jie, Li, Zhuo, Zhu, Yan-Yan, Wang, Hua-Ming
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6471874/
https://www.ncbi.nlm.nih.gov/pubmed/30909633
http://dx.doi.org/10.3390/ma12060974
_version_ 1783412125075505152
author Gao, Yu-Xi
Zou, Jin-Wen
Wang, Xiao-Feng
Yang, Jie
Li, Zhuo
Zhu, Yan-Yan
Wang, Hua-Ming
author_facet Gao, Yu-Xi
Zou, Jin-Wen
Wang, Xiao-Feng
Yang, Jie
Li, Zhuo
Zhu, Yan-Yan
Wang, Hua-Ming
author_sort Gao, Yu-Xi
collection PubMed
description In this paper, a wet-chemical based method was adopted to acquire the uniform dispersion of graphene nanosheets (GNSs) in a powder metallurgy nickel-based superalloy (FGH96) to fabricate a new GNSs reinforced FGH96 metal matrix composite. The surface of the FGH96 powder was modified using a hydrophilic surfactant named polyvinyl alcohol (PVA), which has good wettability and strong hydrogen bonding between the –OH groups of PVA and oxygen groups of GNSs such as –COOH, –CHO, and –OH. It was shown that the GNSs displayed much better dispersion uniformity on the PVA modified FGH96 powder than the unmodified one. The existence of PVA improved the adsorptive capacity of the GNSs attached on the powder surface and prevented the agglomeration in the following thermal preparation process. Consequently, the micro-hardness of PVA modified composite with 0.1 wt.% GNSs reached 497.9 HV, 3.4% higher than the unmodified FGH96 alloy. Therefore, this preparation process could act as the foundation of a common strategy for the fabrication of GNSs in metal matrix composites with good dispersion uniformity, which may have great potential application in aerospace applications.
format Online
Article
Text
id pubmed-6471874
institution National Center for Biotechnology Information
language English
publishDate 2019
publisher MDPI
record_format MEDLINE/PubMed
spelling pubmed-64718742019-04-27 An Approach to the Uniform Dispersion of Graphene Nanosheets in Powder Metallurgy Nickel-Based Superalloy Gao, Yu-Xi Zou, Jin-Wen Wang, Xiao-Feng Yang, Jie Li, Zhuo Zhu, Yan-Yan Wang, Hua-Ming Materials (Basel) Article In this paper, a wet-chemical based method was adopted to acquire the uniform dispersion of graphene nanosheets (GNSs) in a powder metallurgy nickel-based superalloy (FGH96) to fabricate a new GNSs reinforced FGH96 metal matrix composite. The surface of the FGH96 powder was modified using a hydrophilic surfactant named polyvinyl alcohol (PVA), which has good wettability and strong hydrogen bonding between the –OH groups of PVA and oxygen groups of GNSs such as –COOH, –CHO, and –OH. It was shown that the GNSs displayed much better dispersion uniformity on the PVA modified FGH96 powder than the unmodified one. The existence of PVA improved the adsorptive capacity of the GNSs attached on the powder surface and prevented the agglomeration in the following thermal preparation process. Consequently, the micro-hardness of PVA modified composite with 0.1 wt.% GNSs reached 497.9 HV, 3.4% higher than the unmodified FGH96 alloy. Therefore, this preparation process could act as the foundation of a common strategy for the fabrication of GNSs in metal matrix composites with good dispersion uniformity, which may have great potential application in aerospace applications. MDPI 2019-03-24 /pmc/articles/PMC6471874/ /pubmed/30909633 http://dx.doi.org/10.3390/ma12060974 Text en © 2019 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Gao, Yu-Xi
Zou, Jin-Wen
Wang, Xiao-Feng
Yang, Jie
Li, Zhuo
Zhu, Yan-Yan
Wang, Hua-Ming
An Approach to the Uniform Dispersion of Graphene Nanosheets in Powder Metallurgy Nickel-Based Superalloy
title An Approach to the Uniform Dispersion of Graphene Nanosheets in Powder Metallurgy Nickel-Based Superalloy
title_full An Approach to the Uniform Dispersion of Graphene Nanosheets in Powder Metallurgy Nickel-Based Superalloy
title_fullStr An Approach to the Uniform Dispersion of Graphene Nanosheets in Powder Metallurgy Nickel-Based Superalloy
title_full_unstemmed An Approach to the Uniform Dispersion of Graphene Nanosheets in Powder Metallurgy Nickel-Based Superalloy
title_short An Approach to the Uniform Dispersion of Graphene Nanosheets in Powder Metallurgy Nickel-Based Superalloy
title_sort approach to the uniform dispersion of graphene nanosheets in powder metallurgy nickel-based superalloy
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6471874/
https://www.ncbi.nlm.nih.gov/pubmed/30909633
http://dx.doi.org/10.3390/ma12060974
work_keys_str_mv AT gaoyuxi anapproachtotheuniformdispersionofgraphenenanosheetsinpowdermetallurgynickelbasedsuperalloy
AT zoujinwen anapproachtotheuniformdispersionofgraphenenanosheetsinpowdermetallurgynickelbasedsuperalloy
AT wangxiaofeng anapproachtotheuniformdispersionofgraphenenanosheetsinpowdermetallurgynickelbasedsuperalloy
AT yangjie anapproachtotheuniformdispersionofgraphenenanosheetsinpowdermetallurgynickelbasedsuperalloy
AT lizhuo anapproachtotheuniformdispersionofgraphenenanosheetsinpowdermetallurgynickelbasedsuperalloy
AT zhuyanyan anapproachtotheuniformdispersionofgraphenenanosheetsinpowdermetallurgynickelbasedsuperalloy
AT wanghuaming anapproachtotheuniformdispersionofgraphenenanosheetsinpowdermetallurgynickelbasedsuperalloy
AT gaoyuxi approachtotheuniformdispersionofgraphenenanosheetsinpowdermetallurgynickelbasedsuperalloy
AT zoujinwen approachtotheuniformdispersionofgraphenenanosheetsinpowdermetallurgynickelbasedsuperalloy
AT wangxiaofeng approachtotheuniformdispersionofgraphenenanosheetsinpowdermetallurgynickelbasedsuperalloy
AT yangjie approachtotheuniformdispersionofgraphenenanosheetsinpowdermetallurgynickelbasedsuperalloy
AT lizhuo approachtotheuniformdispersionofgraphenenanosheetsinpowdermetallurgynickelbasedsuperalloy
AT zhuyanyan approachtotheuniformdispersionofgraphenenanosheetsinpowdermetallurgynickelbasedsuperalloy
AT wanghuaming approachtotheuniformdispersionofgraphenenanosheetsinpowdermetallurgynickelbasedsuperalloy