A versatile catalyst system for enantioselective synthesis of 2-substituted 1,4-benzodioxanes

We report the synthesis of enantiomerically enriched 1,4-benzodioxanes containing alkyl, aryl, heteroaryl, and/or carbonyl substituents at the 2-position. The starting 1,4-benzodioxines were readily synthesized via ring closing metathesis using an efficient nitro-Grela catalyst at ppm levels. Excell...

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Detalles Bibliográficos
Autores principales: Chong, Eugene, Qu, Bo, Zhang, Yongda, Cannone, Zachary P., Leung, Joyce C., Tcyrulnikov, Sergei, Nguyen, Khoa D., Haddad, Nizar, Biswas, Soumik, Hou, Xiaowen, Kaczanowska, Katarzyna, Chwalba, Michał, Tracz, Andrzej, Czarnocki, Stefan, Song, Jinhua J., Kozlowski, Marisa C., Senanayake, Chris H.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6472100/
https://www.ncbi.nlm.nih.gov/pubmed/31057761
http://dx.doi.org/10.1039/c8sc05612a

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