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Synthesis and structure of a family of rhodium polystannide clusters [Rh@Sn(10)](3–), [Rh@Sn(12)](3–), [Rh(2)@Sn(17)](6–) and the first triply-fused stannide, [Rh(3)@Sn(24)](5–)
Through relatively subtle changes in reaction conditions, we have been able to isolate four distinct Rh/Sn cluster compounds, [Rh@Sn(10)](3–), [Rh@Sn(12)](3–), [Rh(2)@Sn(17)](6–) and [Rh(3)@Sn(24)](5–), from the reaction of K(4)Sn(9) with [(COE)(2)Rh(μ-Cl)](2)(COE = cyclooctene). The last of these h...
Autores principales: | Liu, Chao, Jin, Xiao, Li, Lei-Jiao, Xu, Jun, McGrady, John E., Sun, Zhong-Ming |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6472436/ https://www.ncbi.nlm.nih.gov/pubmed/31057766 http://dx.doi.org/10.1039/c8sc03948h |
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