Cargando…

A Perspective on Recent Advances in Phosphorene Functionalization and Its Applications in Devices

Phosphorene, the 2D material derived from black phosphorus, has recently attracted a lot of interest for its properties, suitable for applications in materials science. The physical features and the prominent chemical reactivity on its surface render this nanolayered substrate particularly promising...

Descripción completa

Detalles Bibliográficos
Autores principales: Peruzzini, Maurizio, Bini, Roberto, Bolognesi, Margherita, Caporali, Maria, Ceppatelli, Matteo, Cicogna, Francesca, Coiai, Serena, Heun, Stefan, Ienco, Andrea, Benito, Iñigo Iglesias, Kumar, Abhishek, Manca, Gabriele, Passaglia, Elisa, Scelta, Demetrio, Serrano‐Ruiz, Manuel, Telesio, Francesca, Toffanin, Stefano, Vanni, Matteo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6472490/
https://www.ncbi.nlm.nih.gov/pubmed/31007576
http://dx.doi.org/10.1002/ejic.201801219
_version_ 1783412251558936576
author Peruzzini, Maurizio
Bini, Roberto
Bolognesi, Margherita
Caporali, Maria
Ceppatelli, Matteo
Cicogna, Francesca
Coiai, Serena
Heun, Stefan
Ienco, Andrea
Benito, Iñigo Iglesias
Kumar, Abhishek
Manca, Gabriele
Passaglia, Elisa
Scelta, Demetrio
Serrano‐Ruiz, Manuel
Telesio, Francesca
Toffanin, Stefano
Vanni, Matteo
author_facet Peruzzini, Maurizio
Bini, Roberto
Bolognesi, Margherita
Caporali, Maria
Ceppatelli, Matteo
Cicogna, Francesca
Coiai, Serena
Heun, Stefan
Ienco, Andrea
Benito, Iñigo Iglesias
Kumar, Abhishek
Manca, Gabriele
Passaglia, Elisa
Scelta, Demetrio
Serrano‐Ruiz, Manuel
Telesio, Francesca
Toffanin, Stefano
Vanni, Matteo
author_sort Peruzzini, Maurizio
collection PubMed
description Phosphorene, the 2D material derived from black phosphorus, has recently attracted a lot of interest for its properties, suitable for applications in materials science. The physical features and the prominent chemical reactivity on its surface render this nanolayered substrate particularly promising for electrical and optoelectronic applications. In addition, being a new potential ligand for metals, it opens the way for a new role of the inorganic chemistry in the 2D world, with special reference to the field of catalysis. The aim of this review is to summarize the state of the art in this subject and to present our most recent results in the preparation, functionalization, and use of phosphorene and its decorated derivatives. We discuss several key points, which are currently under investigation: the synthesis, the characterization by theoretical calculations, the high pressure behavior of black phosphorus, as well as its decoration with nanoparticles and encapsulation in polymers. Finally, device fabrication and electrical transport measurements are overviewed on the basis of recent literature and the new results collected in our laboratories.
format Online
Article
Text
id pubmed-6472490
institution National Center for Biotechnology Information
language English
publishDate 2018
publisher John Wiley and Sons Inc.
record_format MEDLINE/PubMed
spelling pubmed-64724902019-04-19 A Perspective on Recent Advances in Phosphorene Functionalization and Its Applications in Devices Peruzzini, Maurizio Bini, Roberto Bolognesi, Margherita Caporali, Maria Ceppatelli, Matteo Cicogna, Francesca Coiai, Serena Heun, Stefan Ienco, Andrea Benito, Iñigo Iglesias Kumar, Abhishek Manca, Gabriele Passaglia, Elisa Scelta, Demetrio Serrano‐Ruiz, Manuel Telesio, Francesca Toffanin, Stefano Vanni, Matteo Eur J Inorg Chem Microreviews Phosphorene, the 2D material derived from black phosphorus, has recently attracted a lot of interest for its properties, suitable for applications in materials science. The physical features and the prominent chemical reactivity on its surface render this nanolayered substrate particularly promising for electrical and optoelectronic applications. In addition, being a new potential ligand for metals, it opens the way for a new role of the inorganic chemistry in the 2D world, with special reference to the field of catalysis. The aim of this review is to summarize the state of the art in this subject and to present our most recent results in the preparation, functionalization, and use of phosphorene and its decorated derivatives. We discuss several key points, which are currently under investigation: the synthesis, the characterization by theoretical calculations, the high pressure behavior of black phosphorus, as well as its decoration with nanoparticles and encapsulation in polymers. Finally, device fabrication and electrical transport measurements are overviewed on the basis of recent literature and the new results collected in our laboratories. John Wiley and Sons Inc. 2018-12-21 2019-03-31 /pmc/articles/PMC6472490/ /pubmed/31007576 http://dx.doi.org/10.1002/ejic.201801219 Text en © 2019 The Authors. Published by Wiley‐VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the http://creativecommons.org/licenses/by-nc/4.0/ License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited and is not used for commercial purposes.
spellingShingle Microreviews
Peruzzini, Maurizio
Bini, Roberto
Bolognesi, Margherita
Caporali, Maria
Ceppatelli, Matteo
Cicogna, Francesca
Coiai, Serena
Heun, Stefan
Ienco, Andrea
Benito, Iñigo Iglesias
Kumar, Abhishek
Manca, Gabriele
Passaglia, Elisa
Scelta, Demetrio
Serrano‐Ruiz, Manuel
Telesio, Francesca
Toffanin, Stefano
Vanni, Matteo
A Perspective on Recent Advances in Phosphorene Functionalization and Its Applications in Devices
title A Perspective on Recent Advances in Phosphorene Functionalization and Its Applications in Devices
title_full A Perspective on Recent Advances in Phosphorene Functionalization and Its Applications in Devices
title_fullStr A Perspective on Recent Advances in Phosphorene Functionalization and Its Applications in Devices
title_full_unstemmed A Perspective on Recent Advances in Phosphorene Functionalization and Its Applications in Devices
title_short A Perspective on Recent Advances in Phosphorene Functionalization and Its Applications in Devices
title_sort perspective on recent advances in phosphorene functionalization and its applications in devices
topic Microreviews
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6472490/
https://www.ncbi.nlm.nih.gov/pubmed/31007576
http://dx.doi.org/10.1002/ejic.201801219
work_keys_str_mv AT peruzzinimaurizio aperspectiveonrecentadvancesinphosphorenefunctionalizationanditsapplicationsindevices
AT biniroberto aperspectiveonrecentadvancesinphosphorenefunctionalizationanditsapplicationsindevices
AT bolognesimargherita aperspectiveonrecentadvancesinphosphorenefunctionalizationanditsapplicationsindevices
AT caporalimaria aperspectiveonrecentadvancesinphosphorenefunctionalizationanditsapplicationsindevices
AT ceppatellimatteo aperspectiveonrecentadvancesinphosphorenefunctionalizationanditsapplicationsindevices
AT cicognafrancesca aperspectiveonrecentadvancesinphosphorenefunctionalizationanditsapplicationsindevices
AT coiaiserena aperspectiveonrecentadvancesinphosphorenefunctionalizationanditsapplicationsindevices
AT heunstefan aperspectiveonrecentadvancesinphosphorenefunctionalizationanditsapplicationsindevices
AT iencoandrea aperspectiveonrecentadvancesinphosphorenefunctionalizationanditsapplicationsindevices
AT benitoinigoiglesias aperspectiveonrecentadvancesinphosphorenefunctionalizationanditsapplicationsindevices
AT kumarabhishek aperspectiveonrecentadvancesinphosphorenefunctionalizationanditsapplicationsindevices
AT mancagabriele aperspectiveonrecentadvancesinphosphorenefunctionalizationanditsapplicationsindevices
AT passagliaelisa aperspectiveonrecentadvancesinphosphorenefunctionalizationanditsapplicationsindevices
AT sceltademetrio aperspectiveonrecentadvancesinphosphorenefunctionalizationanditsapplicationsindevices
AT serranoruizmanuel aperspectiveonrecentadvancesinphosphorenefunctionalizationanditsapplicationsindevices
AT telesiofrancesca aperspectiveonrecentadvancesinphosphorenefunctionalizationanditsapplicationsindevices
AT toffaninstefano aperspectiveonrecentadvancesinphosphorenefunctionalizationanditsapplicationsindevices
AT vannimatteo aperspectiveonrecentadvancesinphosphorenefunctionalizationanditsapplicationsindevices
AT peruzzinimaurizio perspectiveonrecentadvancesinphosphorenefunctionalizationanditsapplicationsindevices
AT biniroberto perspectiveonrecentadvancesinphosphorenefunctionalizationanditsapplicationsindevices
AT bolognesimargherita perspectiveonrecentadvancesinphosphorenefunctionalizationanditsapplicationsindevices
AT caporalimaria perspectiveonrecentadvancesinphosphorenefunctionalizationanditsapplicationsindevices
AT ceppatellimatteo perspectiveonrecentadvancesinphosphorenefunctionalizationanditsapplicationsindevices
AT cicognafrancesca perspectiveonrecentadvancesinphosphorenefunctionalizationanditsapplicationsindevices
AT coiaiserena perspectiveonrecentadvancesinphosphorenefunctionalizationanditsapplicationsindevices
AT heunstefan perspectiveonrecentadvancesinphosphorenefunctionalizationanditsapplicationsindevices
AT iencoandrea perspectiveonrecentadvancesinphosphorenefunctionalizationanditsapplicationsindevices
AT benitoinigoiglesias perspectiveonrecentadvancesinphosphorenefunctionalizationanditsapplicationsindevices
AT kumarabhishek perspectiveonrecentadvancesinphosphorenefunctionalizationanditsapplicationsindevices
AT mancagabriele perspectiveonrecentadvancesinphosphorenefunctionalizationanditsapplicationsindevices
AT passagliaelisa perspectiveonrecentadvancesinphosphorenefunctionalizationanditsapplicationsindevices
AT sceltademetrio perspectiveonrecentadvancesinphosphorenefunctionalizationanditsapplicationsindevices
AT serranoruizmanuel perspectiveonrecentadvancesinphosphorenefunctionalizationanditsapplicationsindevices
AT telesiofrancesca perspectiveonrecentadvancesinphosphorenefunctionalizationanditsapplicationsindevices
AT toffaninstefano perspectiveonrecentadvancesinphosphorenefunctionalizationanditsapplicationsindevices
AT vannimatteo perspectiveonrecentadvancesinphosphorenefunctionalizationanditsapplicationsindevices