Cargando…
Diffusion Mechanism of Aqueous Solutions and Swelling of Cellulosic Fibers in Silicone Non-Aqueous Dyeing System
The main goal of this article is to study the diffusion mechanism of aqueous solutions and the swelling of cellulosic fibers in the silicone non-aqueous dyeing system via fluorescent labeling. Due to non-polar media only adsorbing on the surface of fiber, cellulosic fiber could not swell as a result...
Autores principales: | , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2019
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6473669/ https://www.ncbi.nlm.nih.gov/pubmed/30960395 http://dx.doi.org/10.3390/polym11030411 |
_version_ | 1783412482260336640 |
---|---|
author | Pei, Liujun Luo, Yuni Gu, Xiaomin Dou, Huashu Wang, Jiping |
author_facet | Pei, Liujun Luo, Yuni Gu, Xiaomin Dou, Huashu Wang, Jiping |
author_sort | Pei, Liujun |
collection | PubMed |
description | The main goal of this article is to study the diffusion mechanism of aqueous solutions and the swelling of cellulosic fibers in the silicone non-aqueous dyeing system via fluorescent labeling. Due to non-polar media only adsorbing on the surface of fiber, cellulosic fiber could not swell as a result of the non-polar media. However, because water molecules can diffuse into the non-crystalline region of the fiber, cellulosic fiber could swell by water which was dispersed or emulsified in a non-aqueous dyeing system. To study the diffusion mechanism of an aqueous solution in the siloxane non-aqueous dyeing system, siloxane non-aqueous media was first diffused to the cellulosic fiber because of its lower surface tension. The resulting aqueous solution took more time to diffuse the surface of the cellulosic fiber, because water molecules must penetrate the siloxane non-aqueous media film. Compared with the fluorescent intensity of the fiber surface, the siloxane film could be re-transferred to the dye bath under the emulsification of the surfactant and the mechanical force. Therefore, a longer diffusion time of the aqueous solution ensured the dyeing feasibility for cellulosic fiber in the non-aqueous dyeing system. |
format | Online Article Text |
id | pubmed-6473669 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2019 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-64736692019-05-03 Diffusion Mechanism of Aqueous Solutions and Swelling of Cellulosic Fibers in Silicone Non-Aqueous Dyeing System Pei, Liujun Luo, Yuni Gu, Xiaomin Dou, Huashu Wang, Jiping Polymers (Basel) Article The main goal of this article is to study the diffusion mechanism of aqueous solutions and the swelling of cellulosic fibers in the silicone non-aqueous dyeing system via fluorescent labeling. Due to non-polar media only adsorbing on the surface of fiber, cellulosic fiber could not swell as a result of the non-polar media. However, because water molecules can diffuse into the non-crystalline region of the fiber, cellulosic fiber could swell by water which was dispersed or emulsified in a non-aqueous dyeing system. To study the diffusion mechanism of an aqueous solution in the siloxane non-aqueous dyeing system, siloxane non-aqueous media was first diffused to the cellulosic fiber because of its lower surface tension. The resulting aqueous solution took more time to diffuse the surface of the cellulosic fiber, because water molecules must penetrate the siloxane non-aqueous media film. Compared with the fluorescent intensity of the fiber surface, the siloxane film could be re-transferred to the dye bath under the emulsification of the surfactant and the mechanical force. Therefore, a longer diffusion time of the aqueous solution ensured the dyeing feasibility for cellulosic fiber in the non-aqueous dyeing system. MDPI 2019-03-04 /pmc/articles/PMC6473669/ /pubmed/30960395 http://dx.doi.org/10.3390/polym11030411 Text en © 2019 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Pei, Liujun Luo, Yuni Gu, Xiaomin Dou, Huashu Wang, Jiping Diffusion Mechanism of Aqueous Solutions and Swelling of Cellulosic Fibers in Silicone Non-Aqueous Dyeing System |
title | Diffusion Mechanism of Aqueous Solutions and Swelling of Cellulosic Fibers in Silicone Non-Aqueous Dyeing System |
title_full | Diffusion Mechanism of Aqueous Solutions and Swelling of Cellulosic Fibers in Silicone Non-Aqueous Dyeing System |
title_fullStr | Diffusion Mechanism of Aqueous Solutions and Swelling of Cellulosic Fibers in Silicone Non-Aqueous Dyeing System |
title_full_unstemmed | Diffusion Mechanism of Aqueous Solutions and Swelling of Cellulosic Fibers in Silicone Non-Aqueous Dyeing System |
title_short | Diffusion Mechanism of Aqueous Solutions and Swelling of Cellulosic Fibers in Silicone Non-Aqueous Dyeing System |
title_sort | diffusion mechanism of aqueous solutions and swelling of cellulosic fibers in silicone non-aqueous dyeing system |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6473669/ https://www.ncbi.nlm.nih.gov/pubmed/30960395 http://dx.doi.org/10.3390/polym11030411 |
work_keys_str_mv | AT peiliujun diffusionmechanismofaqueoussolutionsandswellingofcellulosicfibersinsiliconenonaqueousdyeingsystem AT luoyuni diffusionmechanismofaqueoussolutionsandswellingofcellulosicfibersinsiliconenonaqueousdyeingsystem AT guxiaomin diffusionmechanismofaqueoussolutionsandswellingofcellulosicfibersinsiliconenonaqueousdyeingsystem AT douhuashu diffusionmechanismofaqueoussolutionsandswellingofcellulosicfibersinsiliconenonaqueousdyeingsystem AT wangjiping diffusionmechanismofaqueoussolutionsandswellingofcellulosicfibersinsiliconenonaqueousdyeingsystem |