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Synthetic Routes to Silsesquioxane-Based Systems as Photoactive Materials and Their Precursors

Over the past two decades, organic optoelectronic materials have been considered very promising. The attractiveness of this group of compounds, regardless of their undisputable application potential, lies in the possibility of their use in the construction of organic–inorganic hybrid materials. This...

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Detalles Bibliográficos
Autores principales: Dudziec, Beata, Żak, Patrycja, Marciniec, Bogdan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6473884/
https://www.ncbi.nlm.nih.gov/pubmed/30960488
http://dx.doi.org/10.3390/polym11030504
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author Dudziec, Beata
Żak, Patrycja
Marciniec, Bogdan
author_facet Dudziec, Beata
Żak, Patrycja
Marciniec, Bogdan
author_sort Dudziec, Beata
collection PubMed
description Over the past two decades, organic optoelectronic materials have been considered very promising. The attractiveness of this group of compounds, regardless of their undisputable application potential, lies in the possibility of their use in the construction of organic–inorganic hybrid materials. This class of frameworks also considers nanostructural polyhedral oligomeric silsesquioxanes (POSSs) with “organic coronae” and precisely defined organic architectures between dispersed rigid silica cores. A significant number of papers on the design and development of POSS-based organic optoelectronic as well as photoluminescent (PL) materials have been published recently. In view of the scientific literature abounding with numerous examples of their application (i.e., as OLEDs), the aim of this review is to present efficient synthetic pathways leading to the formation of nanocomposite materials based on silsesquioxane systems that contain organic chromophores of complex nature. A summary of stoichiometric and predominantly catalytic methods for these silsesquioxane-based systems to be applied in the construction of photoactive materials or their precursors is given.
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spelling pubmed-64738842019-04-29 Synthetic Routes to Silsesquioxane-Based Systems as Photoactive Materials and Their Precursors Dudziec, Beata Żak, Patrycja Marciniec, Bogdan Polymers (Basel) Review Over the past two decades, organic optoelectronic materials have been considered very promising. The attractiveness of this group of compounds, regardless of their undisputable application potential, lies in the possibility of their use in the construction of organic–inorganic hybrid materials. This class of frameworks also considers nanostructural polyhedral oligomeric silsesquioxanes (POSSs) with “organic coronae” and precisely defined organic architectures between dispersed rigid silica cores. A significant number of papers on the design and development of POSS-based organic optoelectronic as well as photoluminescent (PL) materials have been published recently. In view of the scientific literature abounding with numerous examples of their application (i.e., as OLEDs), the aim of this review is to present efficient synthetic pathways leading to the formation of nanocomposite materials based on silsesquioxane systems that contain organic chromophores of complex nature. A summary of stoichiometric and predominantly catalytic methods for these silsesquioxane-based systems to be applied in the construction of photoactive materials or their precursors is given. MDPI 2019-03-16 /pmc/articles/PMC6473884/ /pubmed/30960488 http://dx.doi.org/10.3390/polym11030504 Text en © 2019 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Review
Dudziec, Beata
Żak, Patrycja
Marciniec, Bogdan
Synthetic Routes to Silsesquioxane-Based Systems as Photoactive Materials and Their Precursors
title Synthetic Routes to Silsesquioxane-Based Systems as Photoactive Materials and Their Precursors
title_full Synthetic Routes to Silsesquioxane-Based Systems as Photoactive Materials and Their Precursors
title_fullStr Synthetic Routes to Silsesquioxane-Based Systems as Photoactive Materials and Their Precursors
title_full_unstemmed Synthetic Routes to Silsesquioxane-Based Systems as Photoactive Materials and Their Precursors
title_short Synthetic Routes to Silsesquioxane-Based Systems as Photoactive Materials and Their Precursors
title_sort synthetic routes to silsesquioxane-based systems as photoactive materials and their precursors
topic Review
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6473884/
https://www.ncbi.nlm.nih.gov/pubmed/30960488
http://dx.doi.org/10.3390/polym11030504
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