Versatile Multi-Functional Block Copolymers Made by Atom Transfer Radical Polymerization and Post-Synthetic Modification: Switching from Volatile Organic Compound Sensors to Polymeric Surfactants for Water Rheology Control via Hydrolysis

Novel, multipurpose terpolymers based on styrene (PS), tert-butyl methacrylate (tBMA) and glycidyl methacrylate (GMA), have been synthesized via Atom Transfer Radical Polymerization (ATRP). Post-synthetic modification with 1-pyrenemethylamine (AMP) allows non-covalent functionalization of carbon nan...

Descripción completa

Detalles Bibliográficos
Autores principales: Di Sacco, Federico, Pucci, Andrea, Raffa, Patrizio
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2019
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6474081/
https://www.ncbi.nlm.nih.gov/pubmed/30893878
http://dx.doi.org/10.3390/nano9030458
_version_ 1783412574131322880
author Di Sacco, Federico
Pucci, Andrea
Raffa, Patrizio
author_facet Di Sacco, Federico
Pucci, Andrea
Raffa, Patrizio
author_sort Di Sacco, Federico
collection PubMed
description Novel, multipurpose terpolymers based on styrene (PS), tert-butyl methacrylate (tBMA) and glycidyl methacrylate (GMA), have been synthesized via Atom Transfer Radical Polymerization (ATRP). Post-synthetic modification with 1-pyrenemethylamine (AMP) allows non-covalent functionalization of carbon nanotubes, eventually yielding a conductive nanocomposite materials capable of interacting with different Volatile Organic Compounds (VOCs) by electrical resistance variation upon exposure. Moreover, facile hydrolysis of the tBMA group yields polyelectrolytic macrosurfactants with remarkable thickening properties for promising applications in water solution, such as Enhanced Oil Recovery (EOR).
format Online
Article
Text
id pubmed-6474081
institution National Center for Biotechnology Information
language English
publishDate 2019
publisher MDPI
record_format MEDLINE/PubMed
spelling pubmed-64740812019-05-03 Versatile Multi-Functional Block Copolymers Made by Atom Transfer Radical Polymerization and Post-Synthetic Modification: Switching from Volatile Organic Compound Sensors to Polymeric Surfactants for Water Rheology Control via Hydrolysis Di Sacco, Federico Pucci, Andrea Raffa, Patrizio Nanomaterials (Basel) Article Novel, multipurpose terpolymers based on styrene (PS), tert-butyl methacrylate (tBMA) and glycidyl methacrylate (GMA), have been synthesized via Atom Transfer Radical Polymerization (ATRP). Post-synthetic modification with 1-pyrenemethylamine (AMP) allows non-covalent functionalization of carbon nanotubes, eventually yielding a conductive nanocomposite materials capable of interacting with different Volatile Organic Compounds (VOCs) by electrical resistance variation upon exposure. Moreover, facile hydrolysis of the tBMA group yields polyelectrolytic macrosurfactants with remarkable thickening properties for promising applications in water solution, such as Enhanced Oil Recovery (EOR). MDPI 2019-03-19 /pmc/articles/PMC6474081/ /pubmed/30893878 http://dx.doi.org/10.3390/nano9030458 Text en © 2019 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Di Sacco, Federico
Pucci, Andrea
Raffa, Patrizio
Versatile Multi-Functional Block Copolymers Made by Atom Transfer Radical Polymerization and Post-Synthetic Modification: Switching from Volatile Organic Compound Sensors to Polymeric Surfactants for Water Rheology Control via Hydrolysis
title Versatile Multi-Functional Block Copolymers Made by Atom Transfer Radical Polymerization and Post-Synthetic Modification: Switching from Volatile Organic Compound Sensors to Polymeric Surfactants for Water Rheology Control via Hydrolysis
title_full Versatile Multi-Functional Block Copolymers Made by Atom Transfer Radical Polymerization and Post-Synthetic Modification: Switching from Volatile Organic Compound Sensors to Polymeric Surfactants for Water Rheology Control via Hydrolysis
title_fullStr Versatile Multi-Functional Block Copolymers Made by Atom Transfer Radical Polymerization and Post-Synthetic Modification: Switching from Volatile Organic Compound Sensors to Polymeric Surfactants for Water Rheology Control via Hydrolysis
title_full_unstemmed Versatile Multi-Functional Block Copolymers Made by Atom Transfer Radical Polymerization and Post-Synthetic Modification: Switching from Volatile Organic Compound Sensors to Polymeric Surfactants for Water Rheology Control via Hydrolysis
title_short Versatile Multi-Functional Block Copolymers Made by Atom Transfer Radical Polymerization and Post-Synthetic Modification: Switching from Volatile Organic Compound Sensors to Polymeric Surfactants for Water Rheology Control via Hydrolysis
title_sort versatile multi-functional block copolymers made by atom transfer radical polymerization and post-synthetic modification: switching from volatile organic compound sensors to polymeric surfactants for water rheology control via hydrolysis
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6474081/
https://www.ncbi.nlm.nih.gov/pubmed/30893878
http://dx.doi.org/10.3390/nano9030458
work_keys_str_mv AT disaccofederico versatilemultifunctionalblockcopolymersmadebyatomtransferradicalpolymerizationandpostsyntheticmodificationswitchingfromvolatileorganiccompoundsensorstopolymericsurfactantsforwaterrheologycontrolviahydrolysis
AT pucciandrea versatilemultifunctionalblockcopolymersmadebyatomtransferradicalpolymerizationandpostsyntheticmodificationswitchingfromvolatileorganiccompoundsensorstopolymericsurfactantsforwaterrheologycontrolviahydrolysis
AT raffapatrizio versatilemultifunctionalblockcopolymersmadebyatomtransferradicalpolymerizationandpostsyntheticmodificationswitchingfromvolatileorganiccompoundsensorstopolymericsurfactantsforwaterrheologycontrolviahydrolysis

Ejemplares similares