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Seaweed-Liked WS(2)/rGO Enabling Ultralong Cycling Life and Enhanced Rate Capability for Lithium-Ion Batteries

WS(2) is considered as a potential anode material for lithium ion batteries (LIBs) with superior theoretical capacity and stable structure with two-dimensional which facilitates to the transportation and storage of lithium ion. Nevertheless, the commercial recognition of WS(2) has been impeded by th...

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Autores principales: Huang, Yi, Jiang, Yu, Ma, Zhaofei, Zhang, Yan, Zheng, Xianfeng, Yan, Xuemin, Deng, Xiaoqing, Xiao, Wei, Tang, Haolin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6474191/
https://www.ncbi.nlm.nih.gov/pubmed/30897813
http://dx.doi.org/10.3390/nano9030469
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author Huang, Yi
Jiang, Yu
Ma, Zhaofei
Zhang, Yan
Zheng, Xianfeng
Yan, Xuemin
Deng, Xiaoqing
Xiao, Wei
Tang, Haolin
author_facet Huang, Yi
Jiang, Yu
Ma, Zhaofei
Zhang, Yan
Zheng, Xianfeng
Yan, Xuemin
Deng, Xiaoqing
Xiao, Wei
Tang, Haolin
author_sort Huang, Yi
collection PubMed
description WS(2) is considered as a potential anode material for lithium ion batteries (LIBs) with superior theoretical capacity and stable structure with two-dimensional which facilitates to the transportation and storage of lithium ion. Nevertheless, the commercial recognition of WS(2) has been impeded by the intrinsic properties of WS(2), including poor electrical conductivity and large volume expansion. Herein, a seaweed-liked WS(2)/reduced graphene oxide (rGO) composites has been fabricated through a procedure involving the self-assembling of WO(4)(2−), hexadecyl trimethyl ammonium ion with graphene oxide (GO) and the subsequent thermal treatment. The WS(2)/rGO nanocomposite exhibited the outstanding electrochemical property with a stable and remarkable capacity (507.7 mAh·g(−1)) at 1.0 A·g(−1) even after 1000 cycles. This advanced electrochemical property is due to its seaweed-liked feature which can bring in plentiful active sites, ameliorate the stresses arisen from volume variations and increase charge transfer rate.
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spelling pubmed-64741912019-05-01 Seaweed-Liked WS(2)/rGO Enabling Ultralong Cycling Life and Enhanced Rate Capability for Lithium-Ion Batteries Huang, Yi Jiang, Yu Ma, Zhaofei Zhang, Yan Zheng, Xianfeng Yan, Xuemin Deng, Xiaoqing Xiao, Wei Tang, Haolin Nanomaterials (Basel) Article WS(2) is considered as a potential anode material for lithium ion batteries (LIBs) with superior theoretical capacity and stable structure with two-dimensional which facilitates to the transportation and storage of lithium ion. Nevertheless, the commercial recognition of WS(2) has been impeded by the intrinsic properties of WS(2), including poor electrical conductivity and large volume expansion. Herein, a seaweed-liked WS(2)/reduced graphene oxide (rGO) composites has been fabricated through a procedure involving the self-assembling of WO(4)(2−), hexadecyl trimethyl ammonium ion with graphene oxide (GO) and the subsequent thermal treatment. The WS(2)/rGO nanocomposite exhibited the outstanding electrochemical property with a stable and remarkable capacity (507.7 mAh·g(−1)) at 1.0 A·g(−1) even after 1000 cycles. This advanced electrochemical property is due to its seaweed-liked feature which can bring in plentiful active sites, ameliorate the stresses arisen from volume variations and increase charge transfer rate. MDPI 2019-03-20 /pmc/articles/PMC6474191/ /pubmed/30897813 http://dx.doi.org/10.3390/nano9030469 Text en © 2019 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Huang, Yi
Jiang, Yu
Ma, Zhaofei
Zhang, Yan
Zheng, Xianfeng
Yan, Xuemin
Deng, Xiaoqing
Xiao, Wei
Tang, Haolin
Seaweed-Liked WS(2)/rGO Enabling Ultralong Cycling Life and Enhanced Rate Capability for Lithium-Ion Batteries
title Seaweed-Liked WS(2)/rGO Enabling Ultralong Cycling Life and Enhanced Rate Capability for Lithium-Ion Batteries
title_full Seaweed-Liked WS(2)/rGO Enabling Ultralong Cycling Life and Enhanced Rate Capability for Lithium-Ion Batteries
title_fullStr Seaweed-Liked WS(2)/rGO Enabling Ultralong Cycling Life and Enhanced Rate Capability for Lithium-Ion Batteries
title_full_unstemmed Seaweed-Liked WS(2)/rGO Enabling Ultralong Cycling Life and Enhanced Rate Capability for Lithium-Ion Batteries
title_short Seaweed-Liked WS(2)/rGO Enabling Ultralong Cycling Life and Enhanced Rate Capability for Lithium-Ion Batteries
title_sort seaweed-liked ws(2)/rgo enabling ultralong cycling life and enhanced rate capability for lithium-ion batteries
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6474191/
https://www.ncbi.nlm.nih.gov/pubmed/30897813
http://dx.doi.org/10.3390/nano9030469
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