Cargando…
General, Practical and Selective Oxidation Protocol for CF(3)S into CF(3)S(O) Group
A simple and efficient protocol for the oxidation of trifluoromethyl, mono- and difluoromethyl sulfides to the corresponding sulfoxides without over-oxidation to sulfones, using TFPAA prepared in situ from trifluoroacetic acid and 15% H(2)O(2) aqueous solution was developed. The methodology is suita...
Autores principales: | Sokolenko, Liubov V., Orlova, Raisa K., Filatov, Andrey A., Yagupolskii, Yurii L., Magnier, Emmanuel, Pégot, Bruce, Diter, Patrick |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2019
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6479840/ https://www.ncbi.nlm.nih.gov/pubmed/30935001 http://dx.doi.org/10.3390/molecules24071249 |
Ejemplares similares
-
Theoretical insight into OH- and Cl-initiated oxidation of CF(3)OCH(CF(3))(2) and CF(3)OCF(2)CF(2)H & fate of CF(3)OC(X•)(CF(3))(2) and CF(3)OCF(2)CF(2)X• radicals (X=O, O(2))
por: Bai, Feng-Yang, et al.
Publicado: (2017) -
Evaluation of Efficient and Practical Methods for the Preparation of Functionalized Aliphatic Trifluoromethyl Ethers
por: Sokolenko, Taras M., et al.
Publicado: (2017) -
Dichlorotrifluoromethoxyacetic Acid: Preparation and Reactivity †
por: Zriba, Riadh, et al.
Publicado: (2017) -
Trifluoromethyl
Thianthrenium Triflate: A Readily
Available Trifluoromethylating Reagent with Formal CF(3)(+), CF(3)(•), and CF(3)(–) Reactivity
por: Jia, Hao, et al.
Publicado: (2021) -
Access to N−CF(3) Formamides by Reduction of N−CF(3) Carbamoyl Fluorides
por: Zivkovic, Filip G., et al.
Publicado: (2022)