Acid Catalyzed Formation of C–C and C–S Bonds via Excited State Proton Transfer

The behavior of 2-naphthol and 7-bromo-2-naphthol as organic photoacids are exploited in organic synthesis for the preparation of benzyl sulfides (using a trichloroacetimidate derivative as the starting substrate) and polycyclic amines via acid catalyzed condensation of 1,2,3,4-tetrahydroisoquinolin...

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Autores principales: Strada, Alessandro, Fredditori, Mattia, Zanoni, Giuseppe, Protti, Stefano
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2019
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6480163/
https://www.ncbi.nlm.nih.gov/pubmed/30987238
http://dx.doi.org/10.3390/molecules24071318
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author Strada, Alessandro
Fredditori, Mattia
Zanoni, Giuseppe
Protti, Stefano
author_facet Strada, Alessandro
Fredditori, Mattia
Zanoni, Giuseppe
Protti, Stefano
author_sort Strada, Alessandro
collection PubMed
description The behavior of 2-naphthol and 7-bromo-2-naphthol as organic photoacids are exploited in organic synthesis for the preparation of benzyl sulfides (using a trichloroacetimidate derivative as the starting substrate) and polycyclic amines via acid catalyzed condensation of 1,2,3,4-tetrahydroisoquinoline with aldehydes.
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spelling pubmed-64801632019-04-30 Acid Catalyzed Formation of C–C and C–S Bonds via Excited State Proton Transfer Strada, Alessandro Fredditori, Mattia Zanoni, Giuseppe Protti, Stefano Molecules Article The behavior of 2-naphthol and 7-bromo-2-naphthol as organic photoacids are exploited in organic synthesis for the preparation of benzyl sulfides (using a trichloroacetimidate derivative as the starting substrate) and polycyclic amines via acid catalyzed condensation of 1,2,3,4-tetrahydroisoquinoline with aldehydes. MDPI 2019-04-03 /pmc/articles/PMC6480163/ /pubmed/30987238 http://dx.doi.org/10.3390/molecules24071318 Text en © 2019 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Strada, Alessandro
Fredditori, Mattia
Zanoni, Giuseppe
Protti, Stefano
Acid Catalyzed Formation of C–C and C–S Bonds via Excited State Proton Transfer
title Acid Catalyzed Formation of C–C and C–S Bonds via Excited State Proton Transfer
title_full Acid Catalyzed Formation of C–C and C–S Bonds via Excited State Proton Transfer
title_fullStr Acid Catalyzed Formation of C–C and C–S Bonds via Excited State Proton Transfer
title_full_unstemmed Acid Catalyzed Formation of C–C and C–S Bonds via Excited State Proton Transfer
title_short Acid Catalyzed Formation of C–C and C–S Bonds via Excited State Proton Transfer
title_sort acid catalyzed formation of c–c and c–s bonds via excited state proton transfer
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6480163/
https://www.ncbi.nlm.nih.gov/pubmed/30987238
http://dx.doi.org/10.3390/molecules24071318
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AT zanonigiuseppe acidcatalyzedformationofccandcsbondsviaexcitedstateprotontransfer
AT prottistefano acidcatalyzedformationofccandcsbondsviaexcitedstateprotontransfer

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