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A Review of Solvate Ionic Liquids: Physical Parameters and Synthetic Applications
Solvate Ionic Liquids (SILs) are a relatively new class of ionic liquids consisting of a coordinating solvent and salt, that give rise to a chelate complex with very similar properties to ionic liquids. Herein is the exploration of the reported Kamlet-Taft parameters, Gutmann Acceptor numbers and th...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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Frontiers Media S.A.
2019
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6482472/ https://www.ncbi.nlm.nih.gov/pubmed/31058138 http://dx.doi.org/10.3389/fchem.2019.00263 |
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author | Eyckens, Daniel J. Henderson, Luke C. |
author_facet | Eyckens, Daniel J. Henderson, Luke C. |
author_sort | Eyckens, Daniel J. |
collection | PubMed |
description | Solvate Ionic Liquids (SILs) are a relatively new class of ionic liquids consisting of a coordinating solvent and salt, that give rise to a chelate complex with very similar properties to ionic liquids. Herein is the exploration of the reported Kamlet-Taft parameters, Gutmann Acceptor numbers and the investigation of chelating effects through NMR spectroscopy of multiple atomic nuclei. These properties are related to the application of SILs as reaction media for organic reactions. This area is also reviewed here, including the implication in catalysis for the Aldol and Kabachnik-Fields reactions and electrocyclization reactions such as Diels-Alder and [2+2] cycloaddition. Solvate ILs exhibit many interesting properties and hold great potential as a solvent for organic transformations. |
format | Online Article Text |
id | pubmed-6482472 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2019 |
publisher | Frontiers Media S.A. |
record_format | MEDLINE/PubMed |
spelling | pubmed-64824722019-05-03 A Review of Solvate Ionic Liquids: Physical Parameters and Synthetic Applications Eyckens, Daniel J. Henderson, Luke C. Front Chem Chemistry Solvate Ionic Liquids (SILs) are a relatively new class of ionic liquids consisting of a coordinating solvent and salt, that give rise to a chelate complex with very similar properties to ionic liquids. Herein is the exploration of the reported Kamlet-Taft parameters, Gutmann Acceptor numbers and the investigation of chelating effects through NMR spectroscopy of multiple atomic nuclei. These properties are related to the application of SILs as reaction media for organic reactions. This area is also reviewed here, including the implication in catalysis for the Aldol and Kabachnik-Fields reactions and electrocyclization reactions such as Diels-Alder and [2+2] cycloaddition. Solvate ILs exhibit many interesting properties and hold great potential as a solvent for organic transformations. Frontiers Media S.A. 2019-04-18 /pmc/articles/PMC6482472/ /pubmed/31058138 http://dx.doi.org/10.3389/fchem.2019.00263 Text en Copyright © 2019 Eyckens and Henderson. http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) and the copyright owner(s) are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these terms. |
spellingShingle | Chemistry Eyckens, Daniel J. Henderson, Luke C. A Review of Solvate Ionic Liquids: Physical Parameters and Synthetic Applications |
title | A Review of Solvate Ionic Liquids: Physical Parameters and Synthetic Applications |
title_full | A Review of Solvate Ionic Liquids: Physical Parameters and Synthetic Applications |
title_fullStr | A Review of Solvate Ionic Liquids: Physical Parameters and Synthetic Applications |
title_full_unstemmed | A Review of Solvate Ionic Liquids: Physical Parameters and Synthetic Applications |
title_short | A Review of Solvate Ionic Liquids: Physical Parameters and Synthetic Applications |
title_sort | review of solvate ionic liquids: physical parameters and synthetic applications |
topic | Chemistry |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6482472/ https://www.ncbi.nlm.nih.gov/pubmed/31058138 http://dx.doi.org/10.3389/fchem.2019.00263 |
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