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Formation of Mono Oxo Molybdenum(IV) PNP Pincer Complexes: Interplay between Water and Molecular Oxygen
The synthesis of cationic mono oxo Mo(IV) PNP pincer complexes of the type [Mo(PNP(Me)‐iPr)(O)X](+) (X = I, Br) from [Mo(PNP(Me)‐iPr)(CO)X(2)] is described. These compounds are coordinatively unsaturated and feature a strong Mo≡O triple bond. The formation of these complexes proceeds via cationic 14...
Autores principales: | de Aguiar, Sara R. M. M., Öztopcu, Özgür, Troiani, Anna, de Petris, Giulia, Weil, Matthias, Stöger, Berthold, Pittenauer, Ernst, Allmaier, Günter, Veiros, Luis F., Kirchner, Karl |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6485545/ https://www.ncbi.nlm.nih.gov/pubmed/31057330 http://dx.doi.org/10.1002/ejic.201701413 |
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