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Electron Transfer Control of Reductase versus Monooxygenase: Catalytic C–H Bond Hydroxylation and Alkene Epoxidation by Molecular Oxygen
[Image: see text] Catalytic oxidation of organic substrates, using a green oxidant like O(2), has been a long-term goal of the scientific community. In nature, these oxidations are performed by metalloenzymes that generate highly oxidizing species from O(2), which, in turn, can oxidize very stable o...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2019
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6487540/ https://www.ncbi.nlm.nih.gov/pubmed/31041387 http://dx.doi.org/10.1021/acscentsci.9b00046 |