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Synergic Deprotonation Generates Alkali‐Metal Salts of Tethered Fluorenide‐NHC Ligands Co‐Complexed to Alkali‐Metal Amides

Synergic combinations of alkali‐metal hydrocarbyl/amide reagents were used to synthesise saturated N‐heterocyclic carbene (NHC) ligands tethered to a fluorenide anion through deprotonation of a spirocyclic precursor, whereas conventional bases were not successful. The Li(2) derivatives displayed a b...

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Detalles Bibliográficos
Autores principales: Evans, Kieren J., Mansell, Stephen M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6492165/
https://www.ncbi.nlm.nih.gov/pubmed/30667554
http://dx.doi.org/10.1002/chem.201806278

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