Photoredox‐Catalyzed Cyclobutane Synthesis by a Deboronative Radical Addition–Polar Cyclization Cascade

Photoredox‐catalyzed methylcyclobutanations of alkylboronic esters are described. The reactions proceed through single‐electron transfer induced deboronative radical addition to an electron‐deficient alkene followed by single‐electron reduction and polar 4‐exo‐tet cyclization with a pendant alkyl ha...

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Detalles Bibliográficos
Autores principales: Shu, Chao, Noble, Adam, Aggarwal, Varinder K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6492184/
https://www.ncbi.nlm.nih.gov/pubmed/30681266
http://dx.doi.org/10.1002/anie.201813917

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6492184/
https://www.ncbi.nlm.nih.gov/pubmed/30681266
http://dx.doi.org/10.1002/anie.201813917

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