Synthesis of unsymmetrical B(2)E(2) and B(2)E(3) heterocycles by borylene insertion into boradichalcogeniranes

We report the selective insertion of a range of borylene fragments into the E–E bonds (E = S, Se, Te) of cyclic boron dichalcogenides. This method provides facile synthetic access to a variety of symmetrical and unsymmetrical four- and five-membered rings.

Detalles Bibliográficos
Autores principales: Liu, Siyuan, Légaré, Marc-André, Hofmann, Alexander, Rempel, Anna, Hagspiel, Stephan, Braunschweig, Holger
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6495701/
https://www.ncbi.nlm.nih.gov/pubmed/31123576
http://dx.doi.org/10.1039/c9sc00657e
Descripción
Sumario:We report the selective insertion of a range of borylene fragments into the E–E bonds (E = S, Se, Te) of cyclic boron dichalcogenides. This method provides facile synthetic access to a variety of symmetrical and unsymmetrical four- and five-membered rings.