Synthesis of unsymmetrical B(2)E(2) and B(2)E(3) heterocycles by borylene insertion into boradichalcogeniranes

We report the selective insertion of a range of borylene fragments into the E–E bonds (E = S, Se, Te) of cyclic boron dichalcogenides. This method provides facile synthetic access to a variety of symmetrical and unsymmetrical four- and five-membered rings.

Detalles Bibliográficos
Autores principales: Liu, Siyuan, Légaré, Marc-André, Hofmann, Alexander, Rempel, Anna, Hagspiel, Stephan, Braunschweig, Holger
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6495701/
https://www.ncbi.nlm.nih.gov/pubmed/31123576
http://dx.doi.org/10.1039/c9sc00657e
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author Liu, Siyuan
Légaré, Marc-André
Hofmann, Alexander
Rempel, Anna
Hagspiel, Stephan
Braunschweig, Holger
author_facet Liu, Siyuan
Légaré, Marc-André
Hofmann, Alexander
Rempel, Anna
Hagspiel, Stephan
Braunschweig, Holger
author_sort Liu, Siyuan
collection PubMed
description We report the selective insertion of a range of borylene fragments into the E–E bonds (E = S, Se, Te) of cyclic boron dichalcogenides. This method provides facile synthetic access to a variety of symmetrical and unsymmetrical four- and five-membered rings.
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spelling pubmed-64957012019-05-23 Synthesis of unsymmetrical B(2)E(2) and B(2)E(3) heterocycles by borylene insertion into boradichalcogeniranes Liu, Siyuan Légaré, Marc-André Hofmann, Alexander Rempel, Anna Hagspiel, Stephan Braunschweig, Holger Chem Sci Chemistry We report the selective insertion of a range of borylene fragments into the E–E bonds (E = S, Se, Te) of cyclic boron dichalcogenides. This method provides facile synthetic access to a variety of symmetrical and unsymmetrical four- and five-membered rings. Royal Society of Chemistry 2019-03-19 /pmc/articles/PMC6495701/ /pubmed/31123576 http://dx.doi.org/10.1039/c9sc00657e Text en This journal is © The Royal Society of Chemistry 2019 https://creativecommons.org/licenses/by-nc/3.0/This article is freely available. This article is licensed under a Creative Commons Attribution Non Commercial 3.0 Unported Licence (CC BY-NC 3.0)
spellingShingle Chemistry
Liu, Siyuan
Légaré, Marc-André
Hofmann, Alexander
Rempel, Anna
Hagspiel, Stephan
Braunschweig, Holger
Synthesis of unsymmetrical B(2)E(2) and B(2)E(3) heterocycles by borylene insertion into boradichalcogeniranes
title Synthesis of unsymmetrical B(2)E(2) and B(2)E(3) heterocycles by borylene insertion into boradichalcogeniranes
title_full Synthesis of unsymmetrical B(2)E(2) and B(2)E(3) heterocycles by borylene insertion into boradichalcogeniranes
title_fullStr Synthesis of unsymmetrical B(2)E(2) and B(2)E(3) heterocycles by borylene insertion into boradichalcogeniranes
title_full_unstemmed Synthesis of unsymmetrical B(2)E(2) and B(2)E(3) heterocycles by borylene insertion into boradichalcogeniranes
title_short Synthesis of unsymmetrical B(2)E(2) and B(2)E(3) heterocycles by borylene insertion into boradichalcogeniranes
title_sort synthesis of unsymmetrical b(2)e(2) and b(2)e(3) heterocycles by borylene insertion into boradichalcogeniranes
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6495701/
https://www.ncbi.nlm.nih.gov/pubmed/31123576
http://dx.doi.org/10.1039/c9sc00657e
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