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[Cu(3)(C(6)Se(6))](n): The First Highly Conductive 2D π–d Conjugated Coordination Polymer Based on Benzenehexaselenolate
Nanocrystals of a 2D π–d conjugated copper bis(diselenolene) coordination polymer (Cu‐BHS, BHS = benzenehexaselenolate) are synthesized via a simple homogeneous reaction between cupric ions and benzenehexaselenol (H(6)BHS). Its 2D extended hexagonal lattice is confirmed by powder X‐ray diffraction,...
Autores principales: | , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6498113/ https://www.ncbi.nlm.nih.gov/pubmed/31065526 http://dx.doi.org/10.1002/advs.201802235 |
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author | Cui, Yutao Yan, Jie Chen, Zhijun Zhang, Jiajia Zou, Ye Sun, Yimeng Xu, Wei Zhu, Daoben |
author_facet | Cui, Yutao Yan, Jie Chen, Zhijun Zhang, Jiajia Zou, Ye Sun, Yimeng Xu, Wei Zhu, Daoben |
author_sort | Cui, Yutao |
collection | PubMed |
description | Nanocrystals of a 2D π–d conjugated copper bis(diselenolene) coordination polymer (Cu‐BHS, BHS = benzenehexaselenolate) are synthesized via a simple homogeneous reaction between cupric ions and benzenehexaselenol (H(6)BHS). Its 2D extended hexagonal lattice is confirmed by powder X‐ray diffraction, and further characterized by scanning electron microscopy, transmission electron microscopy, and X‐ray photoelectron spectroscopy. The electrical conductivity measured on compressed powder sample reaches 110 S cm(−1) at 300 K, which is among the highest value ever reported for coordination polymers. Furthermore, the intrinsic metallic characteristics of Cu‐BHS are confirmed by ultraviolet photoelectron spectroscopy and band structure calculation. |
format | Online Article Text |
id | pubmed-6498113 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2019 |
publisher | John Wiley and Sons Inc. |
record_format | MEDLINE/PubMed |
spelling | pubmed-64981132019-05-07 [Cu(3)(C(6)Se(6))](n): The First Highly Conductive 2D π–d Conjugated Coordination Polymer Based on Benzenehexaselenolate Cui, Yutao Yan, Jie Chen, Zhijun Zhang, Jiajia Zou, Ye Sun, Yimeng Xu, Wei Zhu, Daoben Adv Sci (Weinh) Communications Nanocrystals of a 2D π–d conjugated copper bis(diselenolene) coordination polymer (Cu‐BHS, BHS = benzenehexaselenolate) are synthesized via a simple homogeneous reaction between cupric ions and benzenehexaselenol (H(6)BHS). Its 2D extended hexagonal lattice is confirmed by powder X‐ray diffraction, and further characterized by scanning electron microscopy, transmission electron microscopy, and X‐ray photoelectron spectroscopy. The electrical conductivity measured on compressed powder sample reaches 110 S cm(−1) at 300 K, which is among the highest value ever reported for coordination polymers. Furthermore, the intrinsic metallic characteristics of Cu‐BHS are confirmed by ultraviolet photoelectron spectroscopy and band structure calculation. John Wiley and Sons Inc. 2019-03-09 /pmc/articles/PMC6498113/ /pubmed/31065526 http://dx.doi.org/10.1002/advs.201802235 Text en © 2019 The Authors. Published by WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim This is an open access article under the terms of the http://creativecommons.org/licenses/by/4.0/ License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited. |
spellingShingle | Communications Cui, Yutao Yan, Jie Chen, Zhijun Zhang, Jiajia Zou, Ye Sun, Yimeng Xu, Wei Zhu, Daoben [Cu(3)(C(6)Se(6))](n): The First Highly Conductive 2D π–d Conjugated Coordination Polymer Based on Benzenehexaselenolate |
title | [Cu(3)(C(6)Se(6))](n): The First Highly Conductive 2D π–d Conjugated Coordination Polymer Based on Benzenehexaselenolate |
title_full | [Cu(3)(C(6)Se(6))](n): The First Highly Conductive 2D π–d Conjugated Coordination Polymer Based on Benzenehexaselenolate |
title_fullStr | [Cu(3)(C(6)Se(6))](n): The First Highly Conductive 2D π–d Conjugated Coordination Polymer Based on Benzenehexaselenolate |
title_full_unstemmed | [Cu(3)(C(6)Se(6))](n): The First Highly Conductive 2D π–d Conjugated Coordination Polymer Based on Benzenehexaselenolate |
title_short | [Cu(3)(C(6)Se(6))](n): The First Highly Conductive 2D π–d Conjugated Coordination Polymer Based on Benzenehexaselenolate |
title_sort | [cu(3)(c(6)se(6))](n): the first highly conductive 2d π–d conjugated coordination polymer based on benzenehexaselenolate |
topic | Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6498113/ https://www.ncbi.nlm.nih.gov/pubmed/31065526 http://dx.doi.org/10.1002/advs.201802235 |
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