[Cu(3)(C(6)Se(6))](n): The First Highly Conductive 2D π–d Conjugated Coordination Polymer Based on Benzenehexaselenolate

Nanocrystals of a 2D π–d conjugated copper bis(diselenolene) coordination polymer (Cu‐BHS, BHS = benzenehexaselenolate) are synthesized via a simple homogeneous reaction between cupric ions and benzenehexaselenol (H(6)BHS). Its 2D extended hexagonal lattice is confirmed by powder X‐ray diffraction,...

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Detalles Bibliográficos
Autores principales: Cui, Yutao, Yan, Jie, Chen, Zhijun, Zhang, Jiajia, Zou, Ye, Sun, Yimeng, Xu, Wei, Zhu, Daoben
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6498113/
https://www.ncbi.nlm.nih.gov/pubmed/31065526
http://dx.doi.org/10.1002/advs.201802235
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author Cui, Yutao
Yan, Jie
Chen, Zhijun
Zhang, Jiajia
Zou, Ye
Sun, Yimeng
Xu, Wei
Zhu, Daoben
author_facet Cui, Yutao
Yan, Jie
Chen, Zhijun
Zhang, Jiajia
Zou, Ye
Sun, Yimeng
Xu, Wei
Zhu, Daoben
author_sort Cui, Yutao
collection PubMed
description Nanocrystals of a 2D π–d conjugated copper bis(diselenolene) coordination polymer (Cu‐BHS, BHS = benzenehexaselenolate) are synthesized via a simple homogeneous reaction between cupric ions and benzenehexaselenol (H(6)BHS). Its 2D extended hexagonal lattice is confirmed by powder X‐ray diffraction, and further characterized by scanning electron microscopy, transmission electron microscopy, and X‐ray photoelectron spectroscopy. The electrical conductivity measured on compressed powder sample reaches 110 S cm(−1) at 300 K, which is among the highest value ever reported for coordination polymers. Furthermore, the intrinsic metallic characteristics of Cu‐BHS are confirmed by ultraviolet photoelectron spectroscopy and band structure calculation.
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spelling pubmed-64981132019-05-07 [Cu(3)(C(6)Se(6))](n): The First Highly Conductive 2D π–d Conjugated Coordination Polymer Based on Benzenehexaselenolate Cui, Yutao Yan, Jie Chen, Zhijun Zhang, Jiajia Zou, Ye Sun, Yimeng Xu, Wei Zhu, Daoben Adv Sci (Weinh) Communications Nanocrystals of a 2D π–d conjugated copper bis(diselenolene) coordination polymer (Cu‐BHS, BHS = benzenehexaselenolate) are synthesized via a simple homogeneous reaction between cupric ions and benzenehexaselenol (H(6)BHS). Its 2D extended hexagonal lattice is confirmed by powder X‐ray diffraction, and further characterized by scanning electron microscopy, transmission electron microscopy, and X‐ray photoelectron spectroscopy. The electrical conductivity measured on compressed powder sample reaches 110 S cm(−1) at 300 K, which is among the highest value ever reported for coordination polymers. Furthermore, the intrinsic metallic characteristics of Cu‐BHS are confirmed by ultraviolet photoelectron spectroscopy and band structure calculation. John Wiley and Sons Inc. 2019-03-09 /pmc/articles/PMC6498113/ /pubmed/31065526 http://dx.doi.org/10.1002/advs.201802235 Text en © 2019 The Authors. Published by WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim This is an open access article under the terms of the http://creativecommons.org/licenses/by/4.0/ License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
spellingShingle Communications
Cui, Yutao
Yan, Jie
Chen, Zhijun
Zhang, Jiajia
Zou, Ye
Sun, Yimeng
Xu, Wei
Zhu, Daoben
[Cu(3)(C(6)Se(6))](n): The First Highly Conductive 2D π–d Conjugated Coordination Polymer Based on Benzenehexaselenolate
title [Cu(3)(C(6)Se(6))](n): The First Highly Conductive 2D π–d Conjugated Coordination Polymer Based on Benzenehexaselenolate
title_full [Cu(3)(C(6)Se(6))](n): The First Highly Conductive 2D π–d Conjugated Coordination Polymer Based on Benzenehexaselenolate
title_fullStr [Cu(3)(C(6)Se(6))](n): The First Highly Conductive 2D π–d Conjugated Coordination Polymer Based on Benzenehexaselenolate
title_full_unstemmed [Cu(3)(C(6)Se(6))](n): The First Highly Conductive 2D π–d Conjugated Coordination Polymer Based on Benzenehexaselenolate
title_short [Cu(3)(C(6)Se(6))](n): The First Highly Conductive 2D π–d Conjugated Coordination Polymer Based on Benzenehexaselenolate
title_sort [cu(3)(c(6)se(6))](n): the first highly conductive 2d π–d conjugated coordination polymer based on benzenehexaselenolate
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6498113/
https://www.ncbi.nlm.nih.gov/pubmed/31065526
http://dx.doi.org/10.1002/advs.201802235
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