Decarboxylative hydrazination of unactivated carboxylic acids by cerium photocatalysis

We report the cerium photocatalyzed radical decarboxylative hydrazination of carboxylic acids with di-tert-butylazodicarboxylate (DBAD). The operationally simple protocol provides rapid access to synthetically useful hydrazine derivatives and overcomes current scope limitations in the photoredox-cat...

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Autores principales: Yatham, Veera Reddy, Bellotti, Peter, König, Burkhard
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6498423/
https://www.ncbi.nlm.nih.gov/pubmed/30829348
http://dx.doi.org/10.1039/c9cc00492k
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author Yatham, Veera Reddy
Bellotti, Peter
König, Burkhard
author_facet Yatham, Veera Reddy
Bellotti, Peter
König, Burkhard
author_sort Yatham, Veera Reddy
collection PubMed
description We report the cerium photocatalyzed radical decarboxylative hydrazination of carboxylic acids with di-tert-butylazodicarboxylate (DBAD). The operationally simple protocol provides rapid access to synthetically useful hydrazine derivatives and overcomes current scope limitations in the photoredox-catalyzed decarboxylation of carboxylic acids.
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spelling pubmed-64984232019-05-23 Decarboxylative hydrazination of unactivated carboxylic acids by cerium photocatalysis Yatham, Veera Reddy Bellotti, Peter König, Burkhard Chem Commun (Camb) Chemistry We report the cerium photocatalyzed radical decarboxylative hydrazination of carboxylic acids with di-tert-butylazodicarboxylate (DBAD). The operationally simple protocol provides rapid access to synthetically useful hydrazine derivatives and overcomes current scope limitations in the photoredox-catalyzed decarboxylation of carboxylic acids. Royal Society of Chemistry 2019-03-25 2019-03-04 /pmc/articles/PMC6498423/ /pubmed/30829348 http://dx.doi.org/10.1039/c9cc00492k Text en This journal is © The Royal Society of Chemistry 2019 http://creativecommons.org/licenses/by-nc/3.0/ This article is freely available. This article is licensed under a Creative Commons Attribution Non Commercial 3.0 Unported Licence (CC BY-NC 3.0)
spellingShingle Chemistry
Yatham, Veera Reddy
Bellotti, Peter
König, Burkhard
Decarboxylative hydrazination of unactivated carboxylic acids by cerium photocatalysis
title Decarboxylative hydrazination of unactivated carboxylic acids by cerium photocatalysis
title_full Decarboxylative hydrazination of unactivated carboxylic acids by cerium photocatalysis
title_fullStr Decarboxylative hydrazination of unactivated carboxylic acids by cerium photocatalysis
title_full_unstemmed Decarboxylative hydrazination of unactivated carboxylic acids by cerium photocatalysis
title_short Decarboxylative hydrazination of unactivated carboxylic acids by cerium photocatalysis
title_sort decarboxylative hydrazination of unactivated carboxylic acids by cerium photocatalysis
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6498423/
https://www.ncbi.nlm.nih.gov/pubmed/30829348
http://dx.doi.org/10.1039/c9cc00492k
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AT bellottipeter decarboxylativehydrazinationofunactivatedcarboxylicacidsbyceriumphotocatalysis
AT konigburkhard decarboxylativehydrazinationofunactivatedcarboxylicacidsbyceriumphotocatalysis

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