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Synthetic studies toward citrinadin A: construction of the pentacyclic core

This manuscript describes the preparation of an advanced intermediate toward the total synthesis of citrinadin A featuring a [3+2] cycloaddition employing in situ generation of the dipole.

Detalles Bibliográficos
Autores principales: McCallum, Monica E., Smith, Genessa M., Matsumaru, Takanori, Kong, Ke, Enquist, John A., Wood, John L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6501190/
https://www.ncbi.nlm.nih.gov/pubmed/26956798
http://dx.doi.org/10.1038/ja.2016.25
Descripción
Sumario:This manuscript describes the preparation of an advanced intermediate toward the total synthesis of citrinadin A featuring a [3+2] cycloaddition employing in situ generation of the dipole.