Selective Hydrogenation of Cyclic Imides to Diols and Amines and Its Application in the Development of a Liquid Organic Hydrogen Carrier

[Image: see text] Direct hydrogenation of a broad variety of cyclic imides to diols and amines using a ruthenium catalyst is reported here. We have applied this strategy toward the development of a new liquid organic hydrogen carrier system based on the hydrogenation of bis-cyclic imide that is form...

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Autores principales: Kumar, Amit, Janes, Trevor, Espinosa-Jalapa, Noel Angel, Milstein, David
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2018
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6502447/
https://www.ncbi.nlm.nih.gov/pubmed/29812921
http://dx.doi.org/10.1021/jacs.8b04581
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author Kumar, Amit
Janes, Trevor
Espinosa-Jalapa, Noel Angel
Milstein, David
author_facet Kumar, Amit
Janes, Trevor
Espinosa-Jalapa, Noel Angel
Milstein, David
author_sort Kumar, Amit
collection PubMed
description [Image: see text] Direct hydrogenation of a broad variety of cyclic imides to diols and amines using a ruthenium catalyst is reported here. We have applied this strategy toward the development of a new liquid organic hydrogen carrier system based on the hydrogenation of bis-cyclic imide that is formed by the dehydrogenative coupling of 1,4-butanediol and ethylenediamine using a new ruthenium catalyst. The rechargeable system has a maximum gravimetric hydrogen storage capacity of 6.66 wt%.
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spelling pubmed-65024472019-05-08 Selective Hydrogenation of Cyclic Imides to Diols and Amines and Its Application in the Development of a Liquid Organic Hydrogen Carrier Kumar, Amit Janes, Trevor Espinosa-Jalapa, Noel Angel Milstein, David J Am Chem Soc [Image: see text] Direct hydrogenation of a broad variety of cyclic imides to diols and amines using a ruthenium catalyst is reported here. We have applied this strategy toward the development of a new liquid organic hydrogen carrier system based on the hydrogenation of bis-cyclic imide that is formed by the dehydrogenative coupling of 1,4-butanediol and ethylenediamine using a new ruthenium catalyst. The rechargeable system has a maximum gravimetric hydrogen storage capacity of 6.66 wt%. American Chemical Society 2018-05-29 2018-06-20 /pmc/articles/PMC6502447/ /pubmed/29812921 http://dx.doi.org/10.1021/jacs.8b04581 Text en Copyright © 2018 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
spellingShingle Kumar, Amit
Janes, Trevor
Espinosa-Jalapa, Noel Angel
Milstein, David
Selective Hydrogenation of Cyclic Imides to Diols and Amines and Its Application in the Development of a Liquid Organic Hydrogen Carrier
title Selective Hydrogenation of Cyclic Imides to Diols and Amines and Its Application in the Development of a Liquid Organic Hydrogen Carrier
title_full Selective Hydrogenation of Cyclic Imides to Diols and Amines and Its Application in the Development of a Liquid Organic Hydrogen Carrier
title_fullStr Selective Hydrogenation of Cyclic Imides to Diols and Amines and Its Application in the Development of a Liquid Organic Hydrogen Carrier
title_full_unstemmed Selective Hydrogenation of Cyclic Imides to Diols and Amines and Its Application in the Development of a Liquid Organic Hydrogen Carrier
title_short Selective Hydrogenation of Cyclic Imides to Diols and Amines and Its Application in the Development of a Liquid Organic Hydrogen Carrier
title_sort selective hydrogenation of cyclic imides to diols and amines and its application in the development of a liquid organic hydrogen carrier
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6502447/
https://www.ncbi.nlm.nih.gov/pubmed/29812921
http://dx.doi.org/10.1021/jacs.8b04581
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AT espinosajalapanoelangel selectivehydrogenationofcyclicimidestodiolsandaminesanditsapplicationinthedevelopmentofaliquidorganichydrogencarrier
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