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Highly Selective, Efficient Deoxygenative Hydrogenation of Amides Catalyzed by a Manganese Pincer Complex via Metal–Ligand Cooperation

[Image: see text] Deoxygenative hydrogenation of amides to amines homogeneously catalyzed by a complex of an Earth-abundant metal is presented. This manganese-catalyzed reaction features high efficiency and selectivity. A plausible reaction mechanism, involving metal–ligand cooperation of the mangan...

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Detalles Bibliográficos
Autores principales:	Zou, You-Quan, Chakraborty, Subrata, Nerush, Alexander, Oren, Dror, Diskin-Posner, Yael, Ben-David, Yehoshoa, Milstein, David
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2018
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6503579/ https://www.ncbi.nlm.nih.gov/pubmed/31080688 http://dx.doi.org/10.1021/acscatal.8b02902

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