Crystal structure of N,N′-[(ethane-1,2-di­yl)bis­(aza­nediylcarbono­thio­yl)]bis­(benzamide)

The reaction of benzoyl chloride and ethyl­endi­amine in the presence of potassium thio­cyanate yielded a white solid, C(18)H(18)N(4)O(2)S(2), which consists of two benzoyl­thio­ureido moieties connected by an ethyl­ene chain. The asymmetric unit consists of one half of the mol­ecule, the complete m...

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Autores principales: Samb, Issa, Gaye, Nango, Sylla-Gueye, Rokhaya, Thiam, Elhadj Ibrahima, Gaye, Mohamed, Retailleau, Pascal
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2019
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6505593/
https://www.ncbi.nlm.nih.gov/pubmed/31110803
http://dx.doi.org/10.1107/S205698901900495X
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author Samb, Issa
Gaye, Nango
Sylla-Gueye, Rokhaya
Thiam, Elhadj Ibrahima
Gaye, Mohamed
Retailleau, Pascal
author_facet Samb, Issa
Gaye, Nango
Sylla-Gueye, Rokhaya
Thiam, Elhadj Ibrahima
Gaye, Mohamed
Retailleau, Pascal
author_sort Samb, Issa
collection PubMed
description The reaction of benzoyl chloride and ethyl­endi­amine in the presence of potassium thio­cyanate yielded a white solid, C(18)H(18)N(4)O(2)S(2), which consists of two benzoyl­thio­ureido moieties connected by an ethyl­ene chain. The asymmetric unit consists of one half of the mol­ecule, the complete mol­ecule being generated by crystallographic inversion symmetry. Both thio­urea moieties are in a trans conformation. An intra­molecular N—H⋯O hydrogen bond occurs. In the crystal, C—H⋯S and C—H⋯O hydrogen bonds link the molecules, forming layers parallel to the ac plane.
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spelling pubmed-65055932019-05-20 Crystal structure of N,N′-[(ethane-1,2-di­yl)bis­(aza­nediylcarbono­thio­yl)]bis­(benzamide) Samb, Issa Gaye, Nango Sylla-Gueye, Rokhaya Thiam, Elhadj Ibrahima Gaye, Mohamed Retailleau, Pascal Acta Crystallogr E Crystallogr Commun Research Communications The reaction of benzoyl chloride and ethyl­endi­amine in the presence of potassium thio­cyanate yielded a white solid, C(18)H(18)N(4)O(2)S(2), which consists of two benzoyl­thio­ureido moieties connected by an ethyl­ene chain. The asymmetric unit consists of one half of the mol­ecule, the complete mol­ecule being generated by crystallographic inversion symmetry. Both thio­urea moieties are in a trans conformation. An intra­molecular N—H⋯O hydrogen bond occurs. In the crystal, C—H⋯S and C—H⋯O hydrogen bonds link the molecules, forming layers parallel to the ac plane. International Union of Crystallography 2019-04-18 /pmc/articles/PMC6505593/ /pubmed/31110803 http://dx.doi.org/10.1107/S205698901900495X Text en © Samb et al. 2019 http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/4.0/
spellingShingle Research Communications
Samb, Issa
Gaye, Nango
Sylla-Gueye, Rokhaya
Thiam, Elhadj Ibrahima
Gaye, Mohamed
Retailleau, Pascal
Crystal structure of N,N′-[(ethane-1,2-di­yl)bis­(aza­nediylcarbono­thio­yl)]bis­(benzamide)
title Crystal structure of N,N′-[(ethane-1,2-di­yl)bis­(aza­nediylcarbono­thio­yl)]bis­(benzamide)
title_full Crystal structure of N,N′-[(ethane-1,2-di­yl)bis­(aza­nediylcarbono­thio­yl)]bis­(benzamide)
title_fullStr Crystal structure of N,N′-[(ethane-1,2-di­yl)bis­(aza­nediylcarbono­thio­yl)]bis­(benzamide)
title_full_unstemmed Crystal structure of N,N′-[(ethane-1,2-di­yl)bis­(aza­nediylcarbono­thio­yl)]bis­(benzamide)
title_short Crystal structure of N,N′-[(ethane-1,2-di­yl)bis­(aza­nediylcarbono­thio­yl)]bis­(benzamide)
title_sort crystal structure of n,n′-[(ethane-1,2-di­yl)bis­(aza­nediylcarbono­thio­yl)]bis­(benzamide)
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6505593/
https://www.ncbi.nlm.nih.gov/pubmed/31110803
http://dx.doi.org/10.1107/S205698901900495X
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