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Crystal structure and Hirshfeld surface analysis of (E)-2-[1-hy­droxy-2-(pyridin-2-yl)eth­yl]-4-[2-(4-meth­oxy­phen­yl)diazen-1-yl]phenol

In the title compound, C(20)H(19)N(3)O(3), the configuration about the azo N=N bond is E, and the central benzene ring is inclined to the pyridine ring by 31.43 (8)° and to the 4-meth­oxy­phenyl ring by 4.73 (8)°. In the crystal, mol­ecules are linked by pairs of O—H⋯N hydrogen bonds, forming invers...

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Autores principales: Faizi, Md. Serajul Haque, Sen, Pratik, Saxena, Gyanesh Kumar, Golenya, Irina A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6505601/
https://www.ncbi.nlm.nih.gov/pubmed/31110794
http://dx.doi.org/10.1107/S2056989019004377
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author Faizi, Md. Serajul Haque
Sen, Pratik
Saxena, Gyanesh Kumar
Golenya, Irina A.
author_facet Faizi, Md. Serajul Haque
Sen, Pratik
Saxena, Gyanesh Kumar
Golenya, Irina A.
author_sort Faizi, Md. Serajul Haque
collection PubMed
description In the title compound, C(20)H(19)N(3)O(3), the configuration about the azo N=N bond is E, and the central benzene ring is inclined to the pyridine ring by 31.43 (8)° and to the 4-meth­oxy­phenyl ring by 4.73 (8)°. In the crystal, mol­ecules are linked by pairs of O—H⋯N hydrogen bonds, forming inversion dimers with an R (2) (2)(12) ring motif. The dimers are linked by O—H⋯O and C—H⋯O hydrogen bonds, forming layers parallel to the ac plane. There are C—H⋯π inter­actions present within the layers and between the layers, leading to the formation of a supra­molecular framework. The layers are also linked by offset π–π inter­actions, with an inter­planar distance of 3.416 (2) Å.
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spelling pubmed-65056012019-05-20 Crystal structure and Hirshfeld surface analysis of (E)-2-[1-hy­droxy-2-(pyridin-2-yl)eth­yl]-4-[2-(4-meth­oxy­phen­yl)diazen-1-yl]phenol Faizi, Md. Serajul Haque Sen, Pratik Saxena, Gyanesh Kumar Golenya, Irina A. Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, C(20)H(19)N(3)O(3), the configuration about the azo N=N bond is E, and the central benzene ring is inclined to the pyridine ring by 31.43 (8)° and to the 4-meth­oxy­phenyl ring by 4.73 (8)°. In the crystal, mol­ecules are linked by pairs of O—H⋯N hydrogen bonds, forming inversion dimers with an R (2) (2)(12) ring motif. The dimers are linked by O—H⋯O and C—H⋯O hydrogen bonds, forming layers parallel to the ac plane. There are C—H⋯π inter­actions present within the layers and between the layers, leading to the formation of a supra­molecular framework. The layers are also linked by offset π–π inter­actions, with an inter­planar distance of 3.416 (2) Å. International Union of Crystallography 2019-04-09 /pmc/articles/PMC6505601/ /pubmed/31110794 http://dx.doi.org/10.1107/S2056989019004377 Text en © Faizi et al. 2019 http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/4.0/
spellingShingle Research Communications
Faizi, Md. Serajul Haque
Sen, Pratik
Saxena, Gyanesh Kumar
Golenya, Irina A.
Crystal structure and Hirshfeld surface analysis of (E)-2-[1-hy­droxy-2-(pyridin-2-yl)eth­yl]-4-[2-(4-meth­oxy­phen­yl)diazen-1-yl]phenol
title Crystal structure and Hirshfeld surface analysis of (E)-2-[1-hy­droxy-2-(pyridin-2-yl)eth­yl]-4-[2-(4-meth­oxy­phen­yl)diazen-1-yl]phenol
title_full Crystal structure and Hirshfeld surface analysis of (E)-2-[1-hy­droxy-2-(pyridin-2-yl)eth­yl]-4-[2-(4-meth­oxy­phen­yl)diazen-1-yl]phenol
title_fullStr Crystal structure and Hirshfeld surface analysis of (E)-2-[1-hy­droxy-2-(pyridin-2-yl)eth­yl]-4-[2-(4-meth­oxy­phen­yl)diazen-1-yl]phenol
title_full_unstemmed Crystal structure and Hirshfeld surface analysis of (E)-2-[1-hy­droxy-2-(pyridin-2-yl)eth­yl]-4-[2-(4-meth­oxy­phen­yl)diazen-1-yl]phenol
title_short Crystal structure and Hirshfeld surface analysis of (E)-2-[1-hy­droxy-2-(pyridin-2-yl)eth­yl]-4-[2-(4-meth­oxy­phen­yl)diazen-1-yl]phenol
title_sort crystal structure and hirshfeld surface analysis of (e)-2-[1-hy­droxy-2-(pyridin-2-yl)eth­yl]-4-[2-(4-meth­oxy­phen­yl)diazen-1-yl]phenol
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6505601/
https://www.ncbi.nlm.nih.gov/pubmed/31110794
http://dx.doi.org/10.1107/S2056989019004377
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