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Crystal structure and Hirshfeld surface analysis of (E)-2-[1-hydroxy-2-(pyridin-2-yl)ethyl]-4-[2-(4-methoxyphenyl)diazen-1-yl]phenol
In the title compound, C(20)H(19)N(3)O(3), the configuration about the azo N=N bond is E, and the central benzene ring is inclined to the pyridine ring by 31.43 (8)° and to the 4-methoxyphenyl ring by 4.73 (8)°. In the crystal, molecules are linked by pairs of O—H⋯N hydrogen bonds, forming invers...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6505601/ https://www.ncbi.nlm.nih.gov/pubmed/31110794 http://dx.doi.org/10.1107/S2056989019004377 |
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author | Faizi, Md. Serajul Haque Sen, Pratik Saxena, Gyanesh Kumar Golenya, Irina A. |
author_facet | Faizi, Md. Serajul Haque Sen, Pratik Saxena, Gyanesh Kumar Golenya, Irina A. |
author_sort | Faizi, Md. Serajul Haque |
collection | PubMed |
description | In the title compound, C(20)H(19)N(3)O(3), the configuration about the azo N=N bond is E, and the central benzene ring is inclined to the pyridine ring by 31.43 (8)° and to the 4-methoxyphenyl ring by 4.73 (8)°. In the crystal, molecules are linked by pairs of O—H⋯N hydrogen bonds, forming inversion dimers with an R (2) (2)(12) ring motif. The dimers are linked by O—H⋯O and C—H⋯O hydrogen bonds, forming layers parallel to the ac plane. There are C—H⋯π interactions present within the layers and between the layers, leading to the formation of a supramolecular framework. The layers are also linked by offset π–π interactions, with an interplanar distance of 3.416 (2) Å. |
format | Online Article Text |
id | pubmed-6505601 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2019 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-65056012019-05-20 Crystal structure and Hirshfeld surface analysis of (E)-2-[1-hydroxy-2-(pyridin-2-yl)ethyl]-4-[2-(4-methoxyphenyl)diazen-1-yl]phenol Faizi, Md. Serajul Haque Sen, Pratik Saxena, Gyanesh Kumar Golenya, Irina A. Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, C(20)H(19)N(3)O(3), the configuration about the azo N=N bond is E, and the central benzene ring is inclined to the pyridine ring by 31.43 (8)° and to the 4-methoxyphenyl ring by 4.73 (8)°. In the crystal, molecules are linked by pairs of O—H⋯N hydrogen bonds, forming inversion dimers with an R (2) (2)(12) ring motif. The dimers are linked by O—H⋯O and C—H⋯O hydrogen bonds, forming layers parallel to the ac plane. There are C—H⋯π interactions present within the layers and between the layers, leading to the formation of a supramolecular framework. The layers are also linked by offset π–π interactions, with an interplanar distance of 3.416 (2) Å. International Union of Crystallography 2019-04-09 /pmc/articles/PMC6505601/ /pubmed/31110794 http://dx.doi.org/10.1107/S2056989019004377 Text en © Faizi et al. 2019 http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/4.0/ |
spellingShingle | Research Communications Faizi, Md. Serajul Haque Sen, Pratik Saxena, Gyanesh Kumar Golenya, Irina A. Crystal structure and Hirshfeld surface analysis of (E)-2-[1-hydroxy-2-(pyridin-2-yl)ethyl]-4-[2-(4-methoxyphenyl)diazen-1-yl]phenol |
title | Crystal structure and Hirshfeld surface analysis of (E)-2-[1-hydroxy-2-(pyridin-2-yl)ethyl]-4-[2-(4-methoxyphenyl)diazen-1-yl]phenol |
title_full | Crystal structure and Hirshfeld surface analysis of (E)-2-[1-hydroxy-2-(pyridin-2-yl)ethyl]-4-[2-(4-methoxyphenyl)diazen-1-yl]phenol |
title_fullStr | Crystal structure and Hirshfeld surface analysis of (E)-2-[1-hydroxy-2-(pyridin-2-yl)ethyl]-4-[2-(4-methoxyphenyl)diazen-1-yl]phenol |
title_full_unstemmed | Crystal structure and Hirshfeld surface analysis of (E)-2-[1-hydroxy-2-(pyridin-2-yl)ethyl]-4-[2-(4-methoxyphenyl)diazen-1-yl]phenol |
title_short | Crystal structure and Hirshfeld surface analysis of (E)-2-[1-hydroxy-2-(pyridin-2-yl)ethyl]-4-[2-(4-methoxyphenyl)diazen-1-yl]phenol |
title_sort | crystal structure and hirshfeld surface analysis of (e)-2-[1-hydroxy-2-(pyridin-2-yl)ethyl]-4-[2-(4-methoxyphenyl)diazen-1-yl]phenol |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6505601/ https://www.ncbi.nlm.nih.gov/pubmed/31110794 http://dx.doi.org/10.1107/S2056989019004377 |
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