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Crystal structure of N-{N-[N-(tert-but­oxy­carbon­yl)-l-α-aspart­yl]-l-α-aspart­yl}-l-α-aspartic acid 1(4),2(4),3(4)-trimethyl ester 3(1)-2-oxo-2-phenyl­ethyl ester {Boc-[Asp(OMe)](3)-OPac}

In the title homotripeptide {Boc-[Asp(OMe)](3)-OPac}, C(28)H(37)N(3)O(13), all peptide bonds adopt an s-trans conformation with respect to the N—H and C=O groups. In the crystal, N—H⋯O hydrogen bonds result in an infinite parallel β-sheet structure running along the b-axis direction. The Boc protect...

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Detalles Bibliográficos
Autores principales: Kato, Takuma, Kishimoto, Saki, Asano, Akiko, Doi, Mitsunobu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6505608/
https://www.ncbi.nlm.nih.gov/pubmed/31110791
http://dx.doi.org/10.1107/S2056989019004596

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