(E)-2-(2-Hy­droxy-3-methyl­benzyl­idene)-N-methyl­hydrazine-1-carbo­thio­amide: supra­molecular assemblies in two-dimensions mediated by N—H⋯S and C—H⋯π inter­actions

In the title compound, C(10)H(13)N(3)OS, the azomethine C=N double bond has an E configuration. The phenyl ring and methyl­hydrazine carbo­thio­amide moiety [maximum deviation = 0.008 (2) Å] are twisted slightly with a dihedral angle of 14.88 (10)°. In the crystal, mol­ecules are linked into sheets...

Descripción completa

Detalles Bibliográficos
Autores principales: Arafath, Md. Azharul, Kwong, Huey Chong, Adam, Farook
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2019
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6505611/
https://www.ncbi.nlm.nih.gov/pubmed/31110788
http://dx.doi.org/10.1107/S2056989019004444
_version_ 1783416790773137408
author Arafath, Md. Azharul
Kwong, Huey Chong
Adam, Farook
author_facet Arafath, Md. Azharul
Kwong, Huey Chong
Adam, Farook
author_sort Arafath, Md. Azharul
collection PubMed
description In the title compound, C(10)H(13)N(3)OS, the azomethine C=N double bond has an E configuration. The phenyl ring and methyl­hydrazine carbo­thio­amide moiety [maximum deviation = 0.008 (2) Å] are twisted slightly with a dihedral angle of 14.88 (10)°. In the crystal, mol­ecules are linked into sheets parallel to the ab plane via N—H⋯S hydrogen bonds and C—H⋯π inter­actions.
format Online
Article
Text
id pubmed-6505611
institution National Center for Biotechnology Information
language English
publishDate 2019
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-65056112019-05-20 (E)-2-(2-Hy­droxy-3-methyl­benzyl­idene)-N-methyl­hydrazine-1-carbo­thio­amide: supra­molecular assemblies in two-dimensions mediated by N—H⋯S and C—H⋯π inter­actions Arafath, Md. Azharul Kwong, Huey Chong Adam, Farook Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, C(10)H(13)N(3)OS, the azomethine C=N double bond has an E configuration. The phenyl ring and methyl­hydrazine carbo­thio­amide moiety [maximum deviation = 0.008 (2) Å] are twisted slightly with a dihedral angle of 14.88 (10)°. In the crystal, mol­ecules are linked into sheets parallel to the ab plane via N—H⋯S hydrogen bonds and C—H⋯π inter­actions. International Union of Crystallography 2019-04-05 /pmc/articles/PMC6505611/ /pubmed/31110788 http://dx.doi.org/10.1107/S2056989019004444 Text en © Arafath et al. 2019 http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/4.0/
spellingShingle Research Communications
Arafath, Md. Azharul
Kwong, Huey Chong
Adam, Farook
(E)-2-(2-Hy­droxy-3-methyl­benzyl­idene)-N-methyl­hydrazine-1-carbo­thio­amide: supra­molecular assemblies in two-dimensions mediated by N—H⋯S and C—H⋯π inter­actions
title (E)-2-(2-Hy­droxy-3-methyl­benzyl­idene)-N-methyl­hydrazine-1-carbo­thio­amide: supra­molecular assemblies in two-dimensions mediated by N—H⋯S and C—H⋯π inter­actions
title_full (E)-2-(2-Hy­droxy-3-methyl­benzyl­idene)-N-methyl­hydrazine-1-carbo­thio­amide: supra­molecular assemblies in two-dimensions mediated by N—H⋯S and C—H⋯π inter­actions
title_fullStr (E)-2-(2-Hy­droxy-3-methyl­benzyl­idene)-N-methyl­hydrazine-1-carbo­thio­amide: supra­molecular assemblies in two-dimensions mediated by N—H⋯S and C—H⋯π inter­actions
title_full_unstemmed (E)-2-(2-Hy­droxy-3-methyl­benzyl­idene)-N-methyl­hydrazine-1-carbo­thio­amide: supra­molecular assemblies in two-dimensions mediated by N—H⋯S and C—H⋯π inter­actions
title_short (E)-2-(2-Hy­droxy-3-methyl­benzyl­idene)-N-methyl­hydrazine-1-carbo­thio­amide: supra­molecular assemblies in two-dimensions mediated by N—H⋯S and C—H⋯π inter­actions
title_sort (e)-2-(2-hy­droxy-3-methyl­benzyl­idene)-n-methyl­hydrazine-1-carbo­thio­amide: supra­molecular assemblies in two-dimensions mediated by n—h⋯s and c—h⋯π inter­actions
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6505611/
https://www.ncbi.nlm.nih.gov/pubmed/31110788
http://dx.doi.org/10.1107/S2056989019004444
work_keys_str_mv AT arafathmdazharul e22hydroxy3methylbenzylidenenmethylhydrazine1carbothioamidesupramolecularassembliesintwodimensionsmediatedbynhsandchpinteractions
AT kwonghueychong e22hydroxy3methylbenzylidenenmethylhydrazine1carbothioamidesupramolecularassembliesintwodimensionsmediatedbynhsandchpinteractions
AT adamfarook e22hydroxy3methylbenzylidenenmethylhydrazine1carbothioamidesupramolecularassembliesintwodimensionsmediatedbynhsandchpinteractions

Ejemplares similares