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Chlorido­(2,2′-{[2-(1-methyl-1H-imidazol-2-yl-κN (3))imidazolidine-1,3-diyl-κN]bis­(methyl­ene)}bis­(1-methyl-1H-imidazole-κN (3)))copper(II) perchlorate

In the crystal structure of the title complex, [CuCl(C(17)H(24)N(8))]ClO(4), the copper(II) metal exhibits an N(4)Cl penta­coordinate environment in a distorted square-pyramidal geometry. Coordination to the metal centre occurs through the three 1-methyl­imidazole N atoms from the pendant groups, on...

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Detalles Bibliográficos
Autores principales: Padilha, Diego da Silva, Scarpellini, Marciela
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6505613/
https://www.ncbi.nlm.nih.gov/pubmed/31110783
http://dx.doi.org/10.1107/S2056989019004055
Descripción
Sumario:In the crystal structure of the title complex, [CuCl(C(17)H(24)N(8))]ClO(4), the copper(II) metal exhibits an N(4)Cl penta­coordinate environment in a distorted square-pyramidal geometry. Coordination to the metal centre occurs through the three 1-methyl­imidazole N atoms from the pendant groups, one amine N atom from the imidazolidine moiety and one chlorido anion. Inter­molecular inter­actions take place at two of the 1-methyl-­imidazole rings in the form of parallel-displaced π–π stacking inter­actions forming chains parallel to the a axis. Three O atoms of the perchlorate anion are rotationally disordered between two orientations with occupancies of 0.5.