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Chlorido(2,2′-{[2-(1-methyl-1H-imidazol-2-yl-κN (3))imidazolidine-1,3-diyl-κN]bis(methylene)}bis(1-methyl-1H-imidazole-κN (3)))copper(II) perchlorate
In the crystal structure of the title complex, [CuCl(C(17)H(24)N(8))]ClO(4), the copper(II) metal exhibits an N(4)Cl pentacoordinate environment in a distorted square-pyramidal geometry. Coordination to the metal centre occurs through the three 1-methylimidazole N atoms from the pendant groups, on...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6505613/ https://www.ncbi.nlm.nih.gov/pubmed/31110783 http://dx.doi.org/10.1107/S2056989019004055 |
Sumario: | In the crystal structure of the title complex, [CuCl(C(17)H(24)N(8))]ClO(4), the copper(II) metal exhibits an N(4)Cl pentacoordinate environment in a distorted square-pyramidal geometry. Coordination to the metal centre occurs through the three 1-methylimidazole N atoms from the pendant groups, one amine N atom from the imidazolidine moiety and one chlorido anion. Intermolecular interactions take place at two of the 1-methyl-imidazole rings in the form of parallel-displaced π–π stacking interactions forming chains parallel to the a axis. Three O atoms of the perchlorate anion are rotationally disordered between two orientations with occupancies of 0.5. |
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