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Chlorido(2,2′-{[2-(1-methyl-1H-imidazol-2-yl-κN (3))imidazolidine-1,3-diyl-κN]bis(methylene)}bis(1-methyl-1H-imidazole-κN (3)))copper(II) perchlorate
In the crystal structure of the title complex, [CuCl(C(17)H(24)N(8))]ClO(4), the copper(II) metal exhibits an N(4)Cl pentacoordinate environment in a distorted square-pyramidal geometry. Coordination to the metal centre occurs through the three 1-methylimidazole N atoms from the pendant groups, on...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6505613/ https://www.ncbi.nlm.nih.gov/pubmed/31110783 http://dx.doi.org/10.1107/S2056989019004055 |
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author | Padilha, Diego da Silva Scarpellini, Marciela |
author_facet | Padilha, Diego da Silva Scarpellini, Marciela |
author_sort | Padilha, Diego da Silva |
collection | PubMed |
description | In the crystal structure of the title complex, [CuCl(C(17)H(24)N(8))]ClO(4), the copper(II) metal exhibits an N(4)Cl pentacoordinate environment in a distorted square-pyramidal geometry. Coordination to the metal centre occurs through the three 1-methylimidazole N atoms from the pendant groups, one amine N atom from the imidazolidine moiety and one chlorido anion. Intermolecular interactions take place at two of the 1-methyl-imidazole rings in the form of parallel-displaced π–π stacking interactions forming chains parallel to the a axis. Three O atoms of the perchlorate anion are rotationally disordered between two orientations with occupancies of 0.5. |
format | Online Article Text |
id | pubmed-6505613 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2019 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-65056132019-05-20 Chlorido(2,2′-{[2-(1-methyl-1H-imidazol-2-yl-κN (3))imidazolidine-1,3-diyl-κN]bis(methylene)}bis(1-methyl-1H-imidazole-κN (3)))copper(II) perchlorate Padilha, Diego da Silva Scarpellini, Marciela Acta Crystallogr E Crystallogr Commun Research Communications In the crystal structure of the title complex, [CuCl(C(17)H(24)N(8))]ClO(4), the copper(II) metal exhibits an N(4)Cl pentacoordinate environment in a distorted square-pyramidal geometry. Coordination to the metal centre occurs through the three 1-methylimidazole N atoms from the pendant groups, one amine N atom from the imidazolidine moiety and one chlorido anion. Intermolecular interactions take place at two of the 1-methyl-imidazole rings in the form of parallel-displaced π–π stacking interactions forming chains parallel to the a axis. Three O atoms of the perchlorate anion are rotationally disordered between two orientations with occupancies of 0.5. International Union of Crystallography 2019-04-02 /pmc/articles/PMC6505613/ /pubmed/31110783 http://dx.doi.org/10.1107/S2056989019004055 Text en © Padilha and Scarpellini 2019 http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/4.0/ |
spellingShingle | Research Communications Padilha, Diego da Silva Scarpellini, Marciela Chlorido(2,2′-{[2-(1-methyl-1H-imidazol-2-yl-κN (3))imidazolidine-1,3-diyl-κN]bis(methylene)}bis(1-methyl-1H-imidazole-κN (3)))copper(II) perchlorate |
title | Chlorido(2,2′-{[2-(1-methyl-1H-imidazol-2-yl-κN
(3))imidazolidine-1,3-diyl-κN]bis(methylene)}bis(1-methyl-1H-imidazole-κN
(3)))copper(II) perchlorate |
title_full | Chlorido(2,2′-{[2-(1-methyl-1H-imidazol-2-yl-κN
(3))imidazolidine-1,3-diyl-κN]bis(methylene)}bis(1-methyl-1H-imidazole-κN
(3)))copper(II) perchlorate |
title_fullStr | Chlorido(2,2′-{[2-(1-methyl-1H-imidazol-2-yl-κN
(3))imidazolidine-1,3-diyl-κN]bis(methylene)}bis(1-methyl-1H-imidazole-κN
(3)))copper(II) perchlorate |
title_full_unstemmed | Chlorido(2,2′-{[2-(1-methyl-1H-imidazol-2-yl-κN
(3))imidazolidine-1,3-diyl-κN]bis(methylene)}bis(1-methyl-1H-imidazole-κN
(3)))copper(II) perchlorate |
title_short | Chlorido(2,2′-{[2-(1-methyl-1H-imidazol-2-yl-κN
(3))imidazolidine-1,3-diyl-κN]bis(methylene)}bis(1-methyl-1H-imidazole-κN
(3)))copper(II) perchlorate |
title_sort | chlorido(2,2′-{[2-(1-methyl-1h-imidazol-2-yl-κn
(3))imidazolidine-1,3-diyl-κn]bis(methylene)}bis(1-methyl-1h-imidazole-κn
(3)))copper(ii) perchlorate |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6505613/ https://www.ncbi.nlm.nih.gov/pubmed/31110783 http://dx.doi.org/10.1107/S2056989019004055 |
work_keys_str_mv | AT padilhadiegodasilva chlorido2221methyl1himidazol2ylkn3imidazolidine13diylknbismethylenebis1methyl1himidazolekn3copperiiperchlorate AT scarpellinimarciela chlorido2221methyl1himidazol2ylkn3imidazolidine13diylknbismethylenebis1methyl1himidazolekn3copperiiperchlorate |