Cargando…
Crystal structure of hydroxy scandium nitrate chloride
Each Sc(3+) ion in the title salt, di-μ-hydroxido-bis[triaqua(nitrato-κ(2) O,O′)scandium(III)] dichloride, [Sc(2)(NO(3))(2)(OH)(2)(H(2)O)(6)]Cl(2), is coordinated by a nitrate anion, two hydroxide ions and three water molecules to generate a distorted pentagonal–bipyramidal ScO(7) coordination...
Autores principales: | , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2019
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6505614/ https://www.ncbi.nlm.nih.gov/pubmed/31110781 http://dx.doi.org/10.1107/S2056989019003918 |
_version_ | 1783416791481974784 |
---|---|
author | Sears, Jeremiah Cramer, Roger Boyle, Timothy |
author_facet | Sears, Jeremiah Cramer, Roger Boyle, Timothy |
author_sort | Sears, Jeremiah |
collection | PubMed |
description | Each Sc(3+) ion in the title salt, di-μ-hydroxido-bis[triaqua(nitrato-κ(2) O,O′)scandium(III)] dichloride, [Sc(2)(NO(3))(2)(OH)(2)(H(2)O)(6)]Cl(2), is coordinated by a nitrate anion, two hydroxide ions and three water molecules to generate a distorted pentagonal–bipyramidal ScO(7) coordination polyhedron. The complete {[(NO(3))(μ-OH)Sc(H(2)O)(3)](2)}(2+) ion is generated by crystallographic inversion symmetry. The nitrate anion binds in a bidentate fashion whereas the hydroxide ions are bridged between two Sc centers. Two charge-balancing Cl(−) ions are located in the outer sphere. In the extended structure, O—H⋯O and O—H⋯Cl hydrogen bonds connect the components into a three-dimensional network. |
format | Online Article Text |
id | pubmed-6505614 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2019 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-65056142019-05-20 Crystal structure of hydroxy scandium nitrate chloride Sears, Jeremiah Cramer, Roger Boyle, Timothy Acta Crystallogr E Crystallogr Commun Research Communications Each Sc(3+) ion in the title salt, di-μ-hydroxido-bis[triaqua(nitrato-κ(2) O,O′)scandium(III)] dichloride, [Sc(2)(NO(3))(2)(OH)(2)(H(2)O)(6)]Cl(2), is coordinated by a nitrate anion, two hydroxide ions and three water molecules to generate a distorted pentagonal–bipyramidal ScO(7) coordination polyhedron. The complete {[(NO(3))(μ-OH)Sc(H(2)O)(3)](2)}(2+) ion is generated by crystallographic inversion symmetry. The nitrate anion binds in a bidentate fashion whereas the hydroxide ions are bridged between two Sc centers. Two charge-balancing Cl(−) ions are located in the outer sphere. In the extended structure, O—H⋯O and O—H⋯Cl hydrogen bonds connect the components into a three-dimensional network. International Union of Crystallography 2019-04-02 /pmc/articles/PMC6505614/ /pubmed/31110781 http://dx.doi.org/10.1107/S2056989019003918 Text en © Sears et al. 2019 http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/4.0/ |
spellingShingle | Research Communications Sears, Jeremiah Cramer, Roger Boyle, Timothy Crystal structure of hydroxy scandium nitrate chloride |
title | Crystal structure of hydroxy scandium nitrate chloride |
title_full | Crystal structure of hydroxy scandium nitrate chloride |
title_fullStr | Crystal structure of hydroxy scandium nitrate chloride |
title_full_unstemmed | Crystal structure of hydroxy scandium nitrate chloride |
title_short | Crystal structure of hydroxy scandium nitrate chloride |
title_sort | crystal structure of hydroxy scandium nitrate chloride |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6505614/ https://www.ncbi.nlm.nih.gov/pubmed/31110781 http://dx.doi.org/10.1107/S2056989019003918 |
work_keys_str_mv | AT searsjeremiah crystalstructureofhydroxyscandiumnitratechloride AT cramerroger crystalstructureofhydroxyscandiumnitratechloride AT boyletimothy crystalstructureofhydroxyscandiumnitratechloride |