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Crystal structure of hy­droxy scandium nitrate chloride

Each Sc(3+) ion in the title salt, di-μ-hydroxido-bis­[tri­aqua­(nitrato-κ(2) O,O′)scandium(III)] dichloride, [Sc(2)(NO(3))(2)(OH)(2)(H(2)O)(6)]Cl(2), is coordinated by a nitrate anion, two hydroxide ions and three water mol­ecules to generate a distorted penta­gonal–bipyramidal ScO(7) coordination...

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Detalles Bibliográficos
Autores principales: Sears, Jeremiah, Cramer, Roger, Boyle, Timothy
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6505614/
https://www.ncbi.nlm.nih.gov/pubmed/31110781
http://dx.doi.org/10.1107/S2056989019003918
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author Sears, Jeremiah
Cramer, Roger
Boyle, Timothy
author_facet Sears, Jeremiah
Cramer, Roger
Boyle, Timothy
author_sort Sears, Jeremiah
collection PubMed
description Each Sc(3+) ion in the title salt, di-μ-hydroxido-bis­[tri­aqua­(nitrato-κ(2) O,O′)scandium(III)] dichloride, [Sc(2)(NO(3))(2)(OH)(2)(H(2)O)(6)]Cl(2), is coordinated by a nitrate anion, two hydroxide ions and three water mol­ecules to generate a distorted penta­gonal–bipyramidal ScO(7) coordination polyhedron. The complete {[(NO(3))(μ-OH)Sc(H(2)O)(3)](2)}(2+) ion is generated by crystallographic inversion symmetry. The nitrate anion binds in a bidentate fashion whereas the hydroxide ions are bridged between two Sc centers. Two charge-balancing Cl(−) ions are located in the outer sphere. In the extended structure, O—H⋯O and O—H⋯Cl hydrogen bonds connect the components into a three-dimensional network.
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spelling pubmed-65056142019-05-20 Crystal structure of hy­droxy scandium nitrate chloride Sears, Jeremiah Cramer, Roger Boyle, Timothy Acta Crystallogr E Crystallogr Commun Research Communications Each Sc(3+) ion in the title salt, di-μ-hydroxido-bis­[tri­aqua­(nitrato-κ(2) O,O′)scandium(III)] dichloride, [Sc(2)(NO(3))(2)(OH)(2)(H(2)O)(6)]Cl(2), is coordinated by a nitrate anion, two hydroxide ions and three water mol­ecules to generate a distorted penta­gonal–bipyramidal ScO(7) coordination polyhedron. The complete {[(NO(3))(μ-OH)Sc(H(2)O)(3)](2)}(2+) ion is generated by crystallographic inversion symmetry. The nitrate anion binds in a bidentate fashion whereas the hydroxide ions are bridged between two Sc centers. Two charge-balancing Cl(−) ions are located in the outer sphere. In the extended structure, O—H⋯O and O—H⋯Cl hydrogen bonds connect the components into a three-dimensional network. International Union of Crystallography 2019-04-02 /pmc/articles/PMC6505614/ /pubmed/31110781 http://dx.doi.org/10.1107/S2056989019003918 Text en © Sears et al. 2019 http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/4.0/
spellingShingle Research Communications
Sears, Jeremiah
Cramer, Roger
Boyle, Timothy
Crystal structure of hy­droxy scandium nitrate chloride
title Crystal structure of hy­droxy scandium nitrate chloride
title_full Crystal structure of hy­droxy scandium nitrate chloride
title_fullStr Crystal structure of hy­droxy scandium nitrate chloride
title_full_unstemmed Crystal structure of hy­droxy scandium nitrate chloride
title_short Crystal structure of hy­droxy scandium nitrate chloride
title_sort crystal structure of hy­droxy scandium nitrate chloride
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6505614/
https://www.ncbi.nlm.nih.gov/pubmed/31110781
http://dx.doi.org/10.1107/S2056989019003918
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