Crystal structure of 1-hepta­fluoro­tolyl-closo-1,2-dicarbadodeca­borane

The mol­ecular structure of the title compound 1-(2′,3′,5′,6′-tetra­fluoro-4′-trifluoro­methyl­phen­yl)-closo-1,2-dicarbadodeca­borane, C(9)H(11)B(10)F(7), features an intra­molecular ortho-F⋯H2 hydrogen bond [2.11 (2) Å], which is responsible for an orientation of the hepta­fluoro­tolyl substituent...

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Detalles Bibliográficos
Autores principales: Watson, James D., Benton, Amanda, Tricas, Hugo, Rosair, Georgina M., Welch, Alan J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2019
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6509674/
https://www.ncbi.nlm.nih.gov/pubmed/31161066
http://dx.doi.org/10.1107/S2056989019004067
Descripción
Sumario:The mol­ecular structure of the title compound 1-(2′,3′,5′,6′-tetra­fluoro-4′-trifluoro­methyl­phen­yl)-closo-1,2-dicarbadodeca­borane, C(9)H(11)B(10)F(7), features an intra­molecular ortho-F⋯H2 hydrogen bond [2.11 (2) Å], which is responsible for an orientation of the hepta­fluoro­tolyl substituent in which the plane of the aryl ring nearly eclipses the C1—C2 cage connectivity.

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