Crystal structure of 1-hepta­fluoro­tolyl-closo-1,2-dicarbadodeca­borane

The mol­ecular structure of the title compound 1-(2′,3′,5′,6′-tetra­fluoro-4′-trifluoro­methyl­phen­yl)-closo-1,2-dicarbadodeca­borane, C(9)H(11)B(10)F(7), features an intra­molecular ortho-F⋯H2 hydrogen bond [2.11 (2) Å], which is responsible for an orientation of the hepta­fluoro­tolyl substituent...

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Autores principales: Watson, James D., Benton, Amanda, Tricas, Hugo, Rosair, Georgina M., Welch, Alan J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2019
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6509674/
https://www.ncbi.nlm.nih.gov/pubmed/31161066
http://dx.doi.org/10.1107/S2056989019004067
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author Watson, James D.
Benton, Amanda
Tricas, Hugo
Rosair, Georgina M.
Welch, Alan J.
author_facet Watson, James D.
Benton, Amanda
Tricas, Hugo
Rosair, Georgina M.
Welch, Alan J.
author_sort Watson, James D.
collection PubMed
description The mol­ecular structure of the title compound 1-(2′,3′,5′,6′-tetra­fluoro-4′-trifluoro­methyl­phen­yl)-closo-1,2-dicarbadodeca­borane, C(9)H(11)B(10)F(7), features an intra­molecular ortho-F⋯H2 hydrogen bond [2.11 (2) Å], which is responsible for an orientation of the hepta­fluoro­tolyl substituent in which the plane of the aryl ring nearly eclipses the C1—C2 cage connectivity.
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spelling pubmed-65096742019-06-03 Crystal structure of 1-hepta­fluoro­tolyl-closo-1,2-dicarbadodeca­borane Watson, James D. Benton, Amanda Tricas, Hugo Rosair, Georgina M. Welch, Alan J. Acta Crystallogr E Crystallogr Commun Research Communications The mol­ecular structure of the title compound 1-(2′,3′,5′,6′-tetra­fluoro-4′-trifluoro­methyl­phen­yl)-closo-1,2-dicarbadodeca­borane, C(9)H(11)B(10)F(7), features an intra­molecular ortho-F⋯H2 hydrogen bond [2.11 (2) Å], which is responsible for an orientation of the hepta­fluoro­tolyl substituent in which the plane of the aryl ring nearly eclipses the C1—C2 cage connectivity. International Union of Crystallography 2019-03-29 /pmc/articles/PMC6509674/ /pubmed/31161066 http://dx.doi.org/10.1107/S2056989019004067 Text en © Watson et al. 2019 http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/4.0/
spellingShingle Research Communications
Watson, James D.
Benton, Amanda
Tricas, Hugo
Rosair, Georgina M.
Welch, Alan J.
Crystal structure of 1-hepta­fluoro­tolyl-closo-1,2-dicarbadodeca­borane
title Crystal structure of 1-hepta­fluoro­tolyl-closo-1,2-dicarbadodeca­borane
title_full Crystal structure of 1-hepta­fluoro­tolyl-closo-1,2-dicarbadodeca­borane
title_fullStr Crystal structure of 1-hepta­fluoro­tolyl-closo-1,2-dicarbadodeca­borane
title_full_unstemmed Crystal structure of 1-hepta­fluoro­tolyl-closo-1,2-dicarbadodeca­borane
title_short Crystal structure of 1-hepta­fluoro­tolyl-closo-1,2-dicarbadodeca­borane
title_sort crystal structure of 1-hepta­fluoro­tolyl-closo-1,2-dicarbadodeca­borane
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6509674/
https://www.ncbi.nlm.nih.gov/pubmed/31161066
http://dx.doi.org/10.1107/S2056989019004067
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