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Synthesis, crystal structure, spectroscopic features and Hirshfeld surfaces of 2-methyl-3-[(2-methyl­phen­yl)carbamo­yl]phenyl acetate

The title compound, C(17)H(17)NO(3), was synthesized, characterized by IR spectroscopy and its crystal structure was determined from single-crystal diffraction data. The asymmetric unit contains two mol­ecules, which adopt different conformations. In one mol­ecule, the acet­oxy and the terminal 2-me...

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Autores principales: Yaman, Mavişe, Cakmak, Şukriye, Dege, Necmi, Odabaşoğlu, Mustafa, Pavlenko, Vadim A., Kutuk, Halil
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6509679/
https://www.ncbi.nlm.nih.gov/pubmed/31161049
http://dx.doi.org/10.1107/S2056989019000021
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author Yaman, Mavişe
Cakmak, Şukriye
Dege, Necmi
Odabaşoğlu, Mustafa
Pavlenko, Vadim A.
Kutuk, Halil
author_facet Yaman, Mavişe
Cakmak, Şukriye
Dege, Necmi
Odabaşoğlu, Mustafa
Pavlenko, Vadim A.
Kutuk, Halil
author_sort Yaman, Mavişe
collection PubMed
description The title compound, C(17)H(17)NO(3), was synthesized, characterized by IR spectroscopy and its crystal structure was determined from single-crystal diffraction data. The asymmetric unit contains two mol­ecules, which adopt different conformations. In one mol­ecule, the acet­oxy and the terminal 2-methyl­phenyl groups are positioned on opposite sides of the plane formed by the central benzene ring, whereas in the other mol­ecule they lie on the same side of this plane. In the crystal, the mol­ecules are linked through strong N—H⋯O hydrogen bonds into chains along [010]. Hirshfeld surface analysis and fingerprint plots were used to investigate the inter­molecular inter­actions in the solid state.
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spelling pubmed-65096792019-06-03 Synthesis, crystal structure, spectroscopic features and Hirshfeld surfaces of 2-methyl-3-[(2-methyl­phen­yl)carbamo­yl]phenyl acetate Yaman, Mavişe Cakmak, Şukriye Dege, Necmi Odabaşoğlu, Mustafa Pavlenko, Vadim A. Kutuk, Halil Acta Crystallogr E Crystallogr Commun Research Communications The title compound, C(17)H(17)NO(3), was synthesized, characterized by IR spectroscopy and its crystal structure was determined from single-crystal diffraction data. The asymmetric unit contains two mol­ecules, which adopt different conformations. In one mol­ecule, the acet­oxy and the terminal 2-methyl­phenyl groups are positioned on opposite sides of the plane formed by the central benzene ring, whereas in the other mol­ecule they lie on the same side of this plane. In the crystal, the mol­ecules are linked through strong N—H⋯O hydrogen bonds into chains along [010]. Hirshfeld surface analysis and fingerprint plots were used to investigate the inter­molecular inter­actions in the solid state. International Union of Crystallography 2019-03-05 /pmc/articles/PMC6509679/ /pubmed/31161049 http://dx.doi.org/10.1107/S2056989019000021 Text en © Yaman et al. 2019 http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/4.0/
spellingShingle Research Communications
Yaman, Mavişe
Cakmak, Şukriye
Dege, Necmi
Odabaşoğlu, Mustafa
Pavlenko, Vadim A.
Kutuk, Halil
Synthesis, crystal structure, spectroscopic features and Hirshfeld surfaces of 2-methyl-3-[(2-methyl­phen­yl)carbamo­yl]phenyl acetate
title Synthesis, crystal structure, spectroscopic features and Hirshfeld surfaces of 2-methyl-3-[(2-methyl­phen­yl)carbamo­yl]phenyl acetate
title_full Synthesis, crystal structure, spectroscopic features and Hirshfeld surfaces of 2-methyl-3-[(2-methyl­phen­yl)carbamo­yl]phenyl acetate
title_fullStr Synthesis, crystal structure, spectroscopic features and Hirshfeld surfaces of 2-methyl-3-[(2-methyl­phen­yl)carbamo­yl]phenyl acetate
title_full_unstemmed Synthesis, crystal structure, spectroscopic features and Hirshfeld surfaces of 2-methyl-3-[(2-methyl­phen­yl)carbamo­yl]phenyl acetate
title_short Synthesis, crystal structure, spectroscopic features and Hirshfeld surfaces of 2-methyl-3-[(2-methyl­phen­yl)carbamo­yl]phenyl acetate
title_sort synthesis, crystal structure, spectroscopic features and hirshfeld surfaces of 2-methyl-3-[(2-methyl­phen­yl)carbamo­yl]phenyl acetate
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6509679/
https://www.ncbi.nlm.nih.gov/pubmed/31161049
http://dx.doi.org/10.1107/S2056989019000021
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