Crystal structure of NiFe(CO)(5)[tris(pyridyl­meth­yl)aza­phosphatrane]: a synthetic mimic of the NiFe hydrogenase active site incorporating a pendant pyridine base

The reaction of Ni(TPAP)(COD) {where TPAP = [(NC(5)H(4))CH(2)](3)P(NC(2)H(4))(3)N} with Fe(CO)(5) resulted in the isolation of the title heterobimetallic NiFe(TPAP)(CO)(5) complex di-μ-carbonyl-tricarbon­yl[2,8,9-tris­(pyridin-2-yl­meth­yl)-2,5,8,9-tetra­aza-1-phosphabi­cyclo­[3.3.3]undeca­ne]ironni...

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Detalles Bibliográficos
Autores principales: Sutthirat, Natwara, Ziller, Joseph W., Yang, Jenny Y., Thammavongsy, Zachary
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2019
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6509684/
https://www.ncbi.nlm.nih.gov/pubmed/31161052
http://dx.doi.org/10.1107/S2056989019003256

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