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Chiral diversification through the assembly of achiral phenylacetylene macrocycles with a two-fold bridge

We demonstrate so-called “chiral diversification”, which is a design strategy to create multiple chiral molecules through the assembly and double-bridging of achiral components. We used phenylacetylene macrocycles (PAMs) as an achiral element. In a molecule, two achiral rings of [6]PAM are stacked o...

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Detalles Bibliográficos
Autores principales: Katoono, Ryo, Kusaka, Keiichi, Saito, Yuki, Sakamoto, Kazuki, Suzuki, Takanori
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6510063/
https://www.ncbi.nlm.nih.gov/pubmed/31160955
http://dx.doi.org/10.1039/c9sc00972h