Stable cyclic (alkyl)(amino)carbene (cAAC) radicals with main group substituents

Isolation and characterization of stable radicals has been a long-pursued quest. While there has been some progress in this field particularly with respect to carbon, radicals involving heavier p-block elements are still considerably sparse. In this review we describe our recent successful efforts o...

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Autores principales: Kundu, Subrata, Sinhababu, Soumen, Chandrasekhar, Vadapalli, Roesky, Herbert W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6510188/
https://www.ncbi.nlm.nih.gov/pubmed/31160949
http://dx.doi.org/10.1039/c9sc01351b
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author Kundu, Subrata
Sinhababu, Soumen
Chandrasekhar, Vadapalli
Roesky, Herbert W.
author_facet Kundu, Subrata
Sinhababu, Soumen
Chandrasekhar, Vadapalli
Roesky, Herbert W.
author_sort Kundu, Subrata
collection PubMed
description Isolation and characterization of stable radicals has been a long-pursued quest. While there has been some progress in this field particularly with respect to carbon, radicals involving heavier p-block elements are still considerably sparse. In this review we describe our recent successful efforts on the isolation of stable p-block element radicals particularly those involving aluminum, silicon, and phosphorus.
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spelling pubmed-65101882019-06-03 Stable cyclic (alkyl)(amino)carbene (cAAC) radicals with main group substituents Kundu, Subrata Sinhababu, Soumen Chandrasekhar, Vadapalli Roesky, Herbert W. Chem Sci Chemistry Isolation and characterization of stable radicals has been a long-pursued quest. While there has been some progress in this field particularly with respect to carbon, radicals involving heavier p-block elements are still considerably sparse. In this review we describe our recent successful efforts on the isolation of stable p-block element radicals particularly those involving aluminum, silicon, and phosphorus. Royal Society of Chemistry 2019-04-08 /pmc/articles/PMC6510188/ /pubmed/31160949 http://dx.doi.org/10.1039/c9sc01351b Text en This journal is © The Royal Society of Chemistry 2019 https://creativecommons.org/licenses/by/3.0/This article is freely available. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence (CC BY 3.0)
spellingShingle Chemistry
Kundu, Subrata
Sinhababu, Soumen
Chandrasekhar, Vadapalli
Roesky, Herbert W.
Stable cyclic (alkyl)(amino)carbene (cAAC) radicals with main group substituents
title Stable cyclic (alkyl)(amino)carbene (cAAC) radicals with main group substituents
title_full Stable cyclic (alkyl)(amino)carbene (cAAC) radicals with main group substituents
title_fullStr Stable cyclic (alkyl)(amino)carbene (cAAC) radicals with main group substituents
title_full_unstemmed Stable cyclic (alkyl)(amino)carbene (cAAC) radicals with main group substituents
title_short Stable cyclic (alkyl)(amino)carbene (cAAC) radicals with main group substituents
title_sort stable cyclic (alkyl)(amino)carbene (caac) radicals with main group substituents
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6510188/
https://www.ncbi.nlm.nih.gov/pubmed/31160949
http://dx.doi.org/10.1039/c9sc01351b
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AT chandrasekharvadapalli stablecyclicalkylaminocarbenecaacradicalswithmaingroupsubstituents
AT roeskyherbertw stablecyclicalkylaminocarbenecaacradicalswithmaingroupsubstituents

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