Cargando…

Stable cyclic (alkyl)(amino)carbene (cAAC) radicals with main group substituents

Isolation and characterization of stable radicals has been a long-pursued quest. While there has been some progress in this field particularly with respect to carbon, radicals involving heavier p-block elements are still considerably sparse. In this review we describe our recent successful efforts o...

Descripción completa

Detalles Bibliográficos
Autores principales:	Kundu, Subrata, Sinhababu, Soumen, Chandrasekhar, Vadapalli, Roesky, Herbert W.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2019
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6510188/ https://www.ncbi.nlm.nih.gov/pubmed/31160949 http://dx.doi.org/10.1039/c9sc01351b

Ejemplares similares

The debut of chiral cyclic (alkyl)(amino)carbenes (CAACs) in enantioselective catalysis
por: Pichon, Delphine, et al.
Publicado: (2019)

(Me)CAAC=N(−): A Cyclic (Alkyl)(Amino)Carbene Imino Ligand
por: Goettel, James T., et al.
Publicado: (2020)

Mesomeric Acceleration Counters Slow Initiation of Ruthenium–CAAC Catalysts for Olefin Metathesis (CAAC = Cyclic (Alkyl)(Amino) Carbene)
por: Ou, Xinrui, et al.
Publicado: (2023)

Direct access to 2-aryl substituted pyrrolinium salts for carbon centre based radicals without pyrrolidine-2-ylidene alias cyclic(alkyl)(amino)carbene (CAAC) as a precursor
por: Mandal, Debdeep, et al.
Publicado: (2019)

CAAC Boranes. Synthesis and characterization of cyclic (alkyl) (amino) carbene borane complexes from BF(3) and BH(3)
por: Monot, Julien, et al.
Publicado: (2010)

Recent Advances in the Domain of Cyclic (Alkyl)(Amino) Carbenes
por: Kumar Kushvaha, Saroj, et al.
Publicado: (2022)

CAAC‐Based Thiele and Schlenk Hydrocarbons
por: Maiti, Avijit, et al.
Publicado: (2020)

An Electron‐Rich Cyclic (Alkyl)(Amino)Carbene on Au(111), Ag(111), and Cu(111) Surfaces
por: Bakker, Anne, et al.
Publicado: (2020)

Cr(i)Cl as well as Cr(+) are stabilised between two cyclic alkyl amino carbenes
por: Samuel, Prinson P., et al.
Publicado: (2015)

cAAC‐Stabilized 9,10‐diboraanthracenes—Acenes with Open‐Shell Singlet Biradical Ground States
por: Saalfrank, Christian, et al.
Publicado: (2020)

Carbodicarbenes and Striking Redox Transitions of their Conjugate Acids: Influence of NHC versus CAAC as Donor Substituents
por: Dolai, Ramapada, et al.
Publicado: (2022)

(CAAC)Pd(py) Catalysts Disproportionate to Pd(CAAC)(2)
por: Marigo, Nicola, et al.
Publicado: (2023)

Gold(I) and Gold(III) Complexes of Cyclic (Alkyl)(amino)carbenes
por: Romanov, Alexander S., et al.
Publicado: (2015)

Activation of Ge−H and Sn−H Bonds with N‐Heterocyclic Carbenes and a Cyclic (Alkyl)(amino)carbene
por: Philipp, Michael S. M., et al.
Publicado: (2022)

A Carbene‐Stabilized Boryl‐Phosphinidene
por: Kumar Sarkar, Samir, et al.
Publicado: (2022)

Towards the Preparation of Stable Cyclic Amino(ylide)Carbenes
por: Steinert, Henning, et al.
Publicado: (2020)

Catalytic and Biocatalytic Iron Porphyrin Carbene Formation: Effects of Binding Mode, Carbene Substituent, Porphyrin Substituent, and Protein Axial Ligand
por: Khade, Rahul L., et al.
Publicado: (2015)

Isolation of Cyclic(Alkyl)(Amino) Carbene–Bismuthinidene Mediated by a Beryllium(0) Complex
por: Wang, Guocang, et al.
Publicado: (2019)

Realizing 1,1‐Dehydration of Secondary Alcohols to Carbenes: Pyrrolidin‐2‐ols as a Source of Cyclic (Alkyl)(Amino)Carbenes
por: Das, Ayan, et al.
Publicado: (2022)

Disclosing Cyclic(Alkyl)(Amino)Carbenes as One‐Electron Reductants: Synthesis of Acyclic(Amino)(Aryl)Carbene‐Based Kekulé Diradicaloids
por: Maiti, Avijit, et al.
Publicado: (2022)

Soluble, crystalline, and thermally stable alkali CO(2)(−) and carbonite (CO(2)(2−)) clusters supported by cyclic(alkyl)(amino) carbenes
por: Freeman, Lucas A., et al.
Publicado: (2021)

Tailoring Carbene–Metal–Amides for Thermally Activated Delayed Fluorescence: A Computationally Guided Study on the Effect of Cyclic (Alkyl)(amino)carbenes
por: Phuoc, Nguyen Le, et al.
Publicado: (2023)

Preparation of Complexes Bearing N‐Alkylated, Anionic or Protic CAACs Through Oxidative Addition of 2‐Halogenoindole Derivatives
por: Termühlen, Sebastian, et al.
Publicado: (2020)

Metal-free dehydropolymerisation of phosphine-boranes using cyclic (alkyl)(amino)carbenes as hydrogen acceptors
por: Oldroyd, Nicola L., et al.
Publicado: (2019)

Mechanistic Understanding of the Heterogeneous, Rhodium-Cyclic (Alkyl)(Amino)Carbene-Catalyzed (Fluoro-)Arene Hydrogenation
por: Moock, Daniel, et al.
Publicado: (2020)

Unexpected Latency of Z-Stereoretentive Ruthenium Olefin Metathesis Catalysts Bearing Unsymmetrical N-heterocyclic Carbene or Cyclic(alkyl)(amino)carbene Ligands
por: Grzesiński, Łukasz, et al.
Publicado: (2022)

Crystal structure of 2-(2,6-diisopropylphenyl)-N,N-diethyl-3,3-dimethyl-2-azaspiro[4.5]decan-1-amine: a diethylamine adduct of a cyclic(alkyl)(amino)carbene (CAAC)
por: Naumann, Roxanne A., et al.
Publicado: (2021)

Cyclopropanations via Heme Carbenes: Basic Mechanism and Effects of Carbene Substituent, Protein Axial Ligand, and Porphyrin Substitution
por: Wei, Yang, et al.
Publicado: (2017)

New Blatter-type radicals from a bench-stable carbene
por: Grant, Jacob A., et al.
Publicado: (2017)

An Unsymmetrical, Cyclic Diborene Based on a Chelating CAAC Ligand and its Small‐Molecule Activation and Rearrangement Chemistry
por: Lu, Wei, et al.
Publicado: (2021)

Bis(Cyclic Alkyl Amino Carbene) Ruthenium Complexes: A Versatile, Highly Efficient Tool for Olefin Metathesis
por: Gawin, Rafał, et al.
Publicado: (2016)

Chromium-catalyzed stereodivergent E- and Z-selective alkyne hydrogenation controlled by cyclic (alkyl)(amino)carbene ligands
por: Ling, Liang, et al.
Publicado: (2023)

The role of alkyl substituents in deazaadenine-based diarylethene photoswitches
por: Sarter, Christopher, et al.
Publicado: (2016)

Aluminium alkyl complexes supported by imino-phosphanamide ligand as precursors for catalytic guanylation reactions of carbodiimides
por: Karmakar, Himadri, et al.
Publicado: (2022)

Influence of Fluorine Substituents on the Electronic Properties of Selenium-N-Heterocyclic Carbene Compounds
por: Jamil, Mohamad Shazwan Shah, et al.
Publicado: (2020)

Ultra‐Long Lived Luminescent Triplet Excited States in Cyclic (Alkyl)(amino)carbene Complexes of Zn(II) Halides
por: Mrózek, Ondřej, et al.
Publicado: (2022)

Stabilization of Linear C(3) by Two Donor Ligands: A Theoretical Study of L‐C(3)‐L (L=PPh(3), NHC(Me), cAAC(Me))
por: Gorantla, Sai Manoj N. V. T., et al.
Publicado: (2020)

Preparation of the Pyridinium Salts Differing in the Length of the N-Alkyl Substituent
por: Marek, Jan, et al.
Publicado: (2010)

EDA-NOCV Analysis of Donor-Base-Stabilized Elusive Monomeric Aluminum Phosphides [(L)P–Al(L′); L, L′ = cAAC(Me), NHC(Me), PMe(3)]
por: Francis, Maria, et al.
Publicado: (2022)

Bonding and stability of dinitrogen-bonded donor base-stabilized Si(0)/Ge(0) species [(cAAC(Me)–Si/Ge)(2)(N(2))]: EDA-NOCV analysis
por: Karnamkkott, Harsha S., et al.
Publicado: (2022)

Cannot write session to /tmp/vufind_sessions/sess_rt696g1e3nqk38otd37d3ah5im