Synthesis of the Tetragonal Phase of Zintl’s NaTl and Its Structure Determination from Powder Diffraction Data

A tetragonal distortion of the long-time known NaTl structure at 298 K was observed in different experimental setups, including Zintl’s original procedure of reducing Tl(I)-iodide by sodium liquid ammonia solutions. The powder diffraction pattern obtained by the high temperature synthesis using clas...

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Autores principales: Tiefenthaler, Susanne, Korber, Nikolaus, Gärtner, Stefanie
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2019
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6515420/
https://www.ncbi.nlm.nih.gov/pubmed/31027267
http://dx.doi.org/10.3390/ma12081356
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author Tiefenthaler, Susanne
Korber, Nikolaus
Gärtner, Stefanie
author_facet Tiefenthaler, Susanne
Korber, Nikolaus
Gärtner, Stefanie
author_sort Tiefenthaler, Susanne
collection PubMed
description A tetragonal distortion of the long-time known NaTl structure at 298 K was observed in different experimental setups, including Zintl’s original procedure of reducing Tl(I)-iodide by sodium liquid ammonia solutions. The powder diffraction pattern obtained by the high temperature synthesis using classical solid-state techniques allowed a model-independent unambiguous structure solution and refinement of tetragonal distorted NaTl (Rp = 0.0179, wRp = 0.0246, R = 0.0477, wR = 0.0527, GooF = 1.24).
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spelling pubmed-65154202019-05-31 Synthesis of the Tetragonal Phase of Zintl’s NaTl and Its Structure Determination from Powder Diffraction Data Tiefenthaler, Susanne Korber, Nikolaus Gärtner, Stefanie Materials (Basel) Article A tetragonal distortion of the long-time known NaTl structure at 298 K was observed in different experimental setups, including Zintl’s original procedure of reducing Tl(I)-iodide by sodium liquid ammonia solutions. The powder diffraction pattern obtained by the high temperature synthesis using classical solid-state techniques allowed a model-independent unambiguous structure solution and refinement of tetragonal distorted NaTl (Rp = 0.0179, wRp = 0.0246, R = 0.0477, wR = 0.0527, GooF = 1.24). MDPI 2019-04-25 /pmc/articles/PMC6515420/ /pubmed/31027267 http://dx.doi.org/10.3390/ma12081356 Text en © 2019 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Tiefenthaler, Susanne
Korber, Nikolaus
Gärtner, Stefanie
Synthesis of the Tetragonal Phase of Zintl’s NaTl and Its Structure Determination from Powder Diffraction Data
title Synthesis of the Tetragonal Phase of Zintl’s NaTl and Its Structure Determination from Powder Diffraction Data
title_full Synthesis of the Tetragonal Phase of Zintl’s NaTl and Its Structure Determination from Powder Diffraction Data
title_fullStr Synthesis of the Tetragonal Phase of Zintl’s NaTl and Its Structure Determination from Powder Diffraction Data
title_full_unstemmed Synthesis of the Tetragonal Phase of Zintl’s NaTl and Its Structure Determination from Powder Diffraction Data
title_short Synthesis of the Tetragonal Phase of Zintl’s NaTl and Its Structure Determination from Powder Diffraction Data
title_sort synthesis of the tetragonal phase of zintl’s natl and its structure determination from powder diffraction data
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6515420/
https://www.ncbi.nlm.nih.gov/pubmed/31027267
http://dx.doi.org/10.3390/ma12081356
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AT korbernikolaus synthesisofthetetragonalphaseofzintlsnatlanditsstructuredeterminationfrompowderdiffractiondata
AT gartnerstefanie synthesisofthetetragonalphaseofzintlsnatlanditsstructuredeterminationfrompowderdiffractiondata

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