Old Molecule, New Chemistry: Exploring Silicon Phthalocyanines as Emerging N-Type Materials in Organic Electronics

Efficient synthesis of silicon phthalocyanines (SiPc) eliminating the strenuous reaction conditions and hazardous reagents required by classical methods is described. Implementation into organic thin-film transistors (OTFTs) affords average electron field-effect mobility of 3.1 × 10(−3) cm(2) V(−1)...

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Detalles Bibliográficos
Autores principales: Yutronkie, Nathan J., Grant, Trevor M., Melville, Owen A., Lessard, Benoît H., Brusso, Jaclyn L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2019
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6515430/
https://www.ncbi.nlm.nih.gov/pubmed/31022864
http://dx.doi.org/10.3390/ma12081334
Descripción
Sumario:Efficient synthesis of silicon phthalocyanines (SiPc) eliminating the strenuous reaction conditions and hazardous reagents required by classical methods is described. Implementation into organic thin-film transistors (OTFTs) affords average electron field-effect mobility of 3.1 × 10(−3) cm(2) V(−1) s(−1) and threshold voltage of 25.6 V for all synthetic routes. These results demonstrate that our novel chemistry can lead to high performing SiPc-based n-type OTFTs.

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