Old Molecule, New Chemistry: Exploring Silicon Phthalocyanines as Emerging N-Type Materials in Organic Electronics

Efficient synthesis of silicon phthalocyanines (SiPc) eliminating the strenuous reaction conditions and hazardous reagents required by classical methods is described. Implementation into organic thin-film transistors (OTFTs) affords average electron field-effect mobility of 3.1 × 10(−3) cm(2) V(−1)...

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Autores principales: Yutronkie, Nathan J., Grant, Trevor M., Melville, Owen A., Lessard, Benoît H., Brusso, Jaclyn L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2019
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6515430/
https://www.ncbi.nlm.nih.gov/pubmed/31022864
http://dx.doi.org/10.3390/ma12081334
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author Yutronkie, Nathan J.
Grant, Trevor M.
Melville, Owen A.
Lessard, Benoît H.
Brusso, Jaclyn L.
author_facet Yutronkie, Nathan J.
Grant, Trevor M.
Melville, Owen A.
Lessard, Benoît H.
Brusso, Jaclyn L.
author_sort Yutronkie, Nathan J.
collection PubMed
description Efficient synthesis of silicon phthalocyanines (SiPc) eliminating the strenuous reaction conditions and hazardous reagents required by classical methods is described. Implementation into organic thin-film transistors (OTFTs) affords average electron field-effect mobility of 3.1 × 10(−3) cm(2) V(−1) s(−1) and threshold voltage of 25.6 V for all synthetic routes. These results demonstrate that our novel chemistry can lead to high performing SiPc-based n-type OTFTs.
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spelling pubmed-65154302019-05-31 Old Molecule, New Chemistry: Exploring Silicon Phthalocyanines as Emerging N-Type Materials in Organic Electronics Yutronkie, Nathan J. Grant, Trevor M. Melville, Owen A. Lessard, Benoît H. Brusso, Jaclyn L. Materials (Basel) Article Efficient synthesis of silicon phthalocyanines (SiPc) eliminating the strenuous reaction conditions and hazardous reagents required by classical methods is described. Implementation into organic thin-film transistors (OTFTs) affords average electron field-effect mobility of 3.1 × 10(−3) cm(2) V(−1) s(−1) and threshold voltage of 25.6 V for all synthetic routes. These results demonstrate that our novel chemistry can lead to high performing SiPc-based n-type OTFTs. MDPI 2019-04-24 /pmc/articles/PMC6515430/ /pubmed/31022864 http://dx.doi.org/10.3390/ma12081334 Text en © 2019 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Yutronkie, Nathan J.
Grant, Trevor M.
Melville, Owen A.
Lessard, Benoît H.
Brusso, Jaclyn L.
Old Molecule, New Chemistry: Exploring Silicon Phthalocyanines as Emerging N-Type Materials in Organic Electronics
title Old Molecule, New Chemistry: Exploring Silicon Phthalocyanines as Emerging N-Type Materials in Organic Electronics
title_full Old Molecule, New Chemistry: Exploring Silicon Phthalocyanines as Emerging N-Type Materials in Organic Electronics
title_fullStr Old Molecule, New Chemistry: Exploring Silicon Phthalocyanines as Emerging N-Type Materials in Organic Electronics
title_full_unstemmed Old Molecule, New Chemistry: Exploring Silicon Phthalocyanines as Emerging N-Type Materials in Organic Electronics
title_short Old Molecule, New Chemistry: Exploring Silicon Phthalocyanines as Emerging N-Type Materials in Organic Electronics
title_sort old molecule, new chemistry: exploring silicon phthalocyanines as emerging n-type materials in organic electronics
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6515430/
https://www.ncbi.nlm.nih.gov/pubmed/31022864
http://dx.doi.org/10.3390/ma12081334
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