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Interconversion of Phosphinyl Radical and Phosphinidene Complexes by Proton Coupled Electron Transfer

The isolable complex [Os(PHMes*)H(PNP)] (Mes*=2,4,6‐(t)Bu(3)C(6)H(3); PNP=N{CHCHP(t)Bu(2)}(2)) exhibits high phosphinyl radical character. This compound offers access to the phosphinidene complex [Os(PMes*)H(PNP)] by P−H proton coupled electron transfer (PCET). The P−H bond dissociation energy (BDE)...

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Detalles Bibliográficos
Autores principales:	Abbenseth, Josh, Delony, Daniel, Neben, Marc C., Würtele, Christian, de Bruin, Bas, Schneider, Sven
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2019
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6519162/ https://www.ncbi.nlm.nih.gov/pubmed/30840783 http://dx.doi.org/10.1002/anie.201901470

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