Cargando…
Chemically Reduced Graphene Oxide-Reinforced Poly(Lactic Acid)/Poly(Ethylene Glycol) Nanocomposites: Preparation, Characterization, and Applications in Electromagnetic Interference Shielding
In this study, a nanocomposite of reduced graphene oxide (RGO) nanofiller-reinforcement poly(lactic acid) (PLA)/poly(ethylene glycol) (PEG) matrix was prepared via the melt blending method. The flexibility of PLA was improved by blending the polymer with a PEG plasticizer as a second polymer. To enh...
Autores principales: | , , , , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2019
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6523337/ https://www.ncbi.nlm.nih.gov/pubmed/30978935 http://dx.doi.org/10.3390/polym11040661 |
_version_ | 1783419310996193280 |
---|---|
author | Ahmad, Ahmad Fahad Aziz, Sidek Ab Abbas, Zulkifly Obaiys, Suzan Jabbar Matori, Khamirul Amin Zaid, Mohd Hafiz Mohd Raad, Haider K. Aliyu, Umar Sa’ad |
author_facet | Ahmad, Ahmad Fahad Aziz, Sidek Ab Abbas, Zulkifly Obaiys, Suzan Jabbar Matori, Khamirul Amin Zaid, Mohd Hafiz Mohd Raad, Haider K. Aliyu, Umar Sa’ad |
author_sort | Ahmad, Ahmad Fahad |
collection | PubMed |
description | In this study, a nanocomposite of reduced graphene oxide (RGO) nanofiller-reinforcement poly(lactic acid) (PLA)/poly(ethylene glycol) (PEG) matrix was prepared via the melt blending method. The flexibility of PLA was improved by blending the polymer with a PEG plasticizer as a second polymer. To enhance the electromagnetic interference shielding properties of the nanocomposite, different RGO wt % were combined with the PLA/PEG blend. Using Fourier-transform infrared (FT-IR) spectroscopy, field emission scanning electron microscopy (FE-SEM) and X-ray diffraction, the structural, microstructure, and morphological properties of the polymer and the RGO/PLA/PEG nanocomposites were examined. These studies showed that the RGO addition did not considerably affect the crystallinity of the resulting nanomaterials. Thermal analysis (TGA) reveals that the addition of RGO highly improved the thermal stability of PLA/PEG nanocomposites. The dielectric properties and electromagnetic interference shielding effectiveness of the synthesized nanocomposites were calculated and showed a higher SE total value than the target value (20 dB). On the other hand, the results showed an increased power loss by increasing the frequency and conversely decreased with an increased percentage of filler. |
format | Online Article Text |
id | pubmed-6523337 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2019 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-65233372019-06-03 Chemically Reduced Graphene Oxide-Reinforced Poly(Lactic Acid)/Poly(Ethylene Glycol) Nanocomposites: Preparation, Characterization, and Applications in Electromagnetic Interference Shielding Ahmad, Ahmad Fahad Aziz, Sidek Ab Abbas, Zulkifly Obaiys, Suzan Jabbar Matori, Khamirul Amin Zaid, Mohd Hafiz Mohd Raad, Haider K. Aliyu, Umar Sa’ad Polymers (Basel) Article In this study, a nanocomposite of reduced graphene oxide (RGO) nanofiller-reinforcement poly(lactic acid) (PLA)/poly(ethylene glycol) (PEG) matrix was prepared via the melt blending method. The flexibility of PLA was improved by blending the polymer with a PEG plasticizer as a second polymer. To enhance the electromagnetic interference shielding properties of the nanocomposite, different RGO wt % were combined with the PLA/PEG blend. Using Fourier-transform infrared (FT-IR) spectroscopy, field emission scanning electron microscopy (FE-SEM) and X-ray diffraction, the structural, microstructure, and morphological properties of the polymer and the RGO/PLA/PEG nanocomposites were examined. These studies showed that the RGO addition did not considerably affect the crystallinity of the resulting nanomaterials. Thermal analysis (TGA) reveals that the addition of RGO highly improved the thermal stability of PLA/PEG nanocomposites. The dielectric properties and electromagnetic interference shielding effectiveness of the synthesized nanocomposites were calculated and showed a higher SE total value than the target value (20 dB). On the other hand, the results showed an increased power loss by increasing the frequency and conversely decreased with an increased percentage of filler. MDPI 2019-04-11 /pmc/articles/PMC6523337/ /pubmed/30978935 http://dx.doi.org/10.3390/polym11040661 Text en © 2019 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Ahmad, Ahmad Fahad Aziz, Sidek Ab Abbas, Zulkifly Obaiys, Suzan Jabbar Matori, Khamirul Amin Zaid, Mohd Hafiz Mohd Raad, Haider K. Aliyu, Umar Sa’ad Chemically Reduced Graphene Oxide-Reinforced Poly(Lactic Acid)/Poly(Ethylene Glycol) Nanocomposites: Preparation, Characterization, and Applications in Electromagnetic Interference Shielding |
title | Chemically Reduced Graphene Oxide-Reinforced Poly(Lactic Acid)/Poly(Ethylene Glycol) Nanocomposites: Preparation, Characterization, and Applications in Electromagnetic Interference Shielding |
title_full | Chemically Reduced Graphene Oxide-Reinforced Poly(Lactic Acid)/Poly(Ethylene Glycol) Nanocomposites: Preparation, Characterization, and Applications in Electromagnetic Interference Shielding |
title_fullStr | Chemically Reduced Graphene Oxide-Reinforced Poly(Lactic Acid)/Poly(Ethylene Glycol) Nanocomposites: Preparation, Characterization, and Applications in Electromagnetic Interference Shielding |
title_full_unstemmed | Chemically Reduced Graphene Oxide-Reinforced Poly(Lactic Acid)/Poly(Ethylene Glycol) Nanocomposites: Preparation, Characterization, and Applications in Electromagnetic Interference Shielding |
title_short | Chemically Reduced Graphene Oxide-Reinforced Poly(Lactic Acid)/Poly(Ethylene Glycol) Nanocomposites: Preparation, Characterization, and Applications in Electromagnetic Interference Shielding |
title_sort | chemically reduced graphene oxide-reinforced poly(lactic acid)/poly(ethylene glycol) nanocomposites: preparation, characterization, and applications in electromagnetic interference shielding |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6523337/ https://www.ncbi.nlm.nih.gov/pubmed/30978935 http://dx.doi.org/10.3390/polym11040661 |
work_keys_str_mv | AT ahmadahmadfahad chemicallyreducedgrapheneoxidereinforcedpolylacticacidpolyethyleneglycolnanocompositespreparationcharacterizationandapplicationsinelectromagneticinterferenceshielding AT azizsidekab chemicallyreducedgrapheneoxidereinforcedpolylacticacidpolyethyleneglycolnanocompositespreparationcharacterizationandapplicationsinelectromagneticinterferenceshielding AT abbaszulkifly chemicallyreducedgrapheneoxidereinforcedpolylacticacidpolyethyleneglycolnanocompositespreparationcharacterizationandapplicationsinelectromagneticinterferenceshielding AT obaiyssuzanjabbar chemicallyreducedgrapheneoxidereinforcedpolylacticacidpolyethyleneglycolnanocompositespreparationcharacterizationandapplicationsinelectromagneticinterferenceshielding AT matorikhamirulamin chemicallyreducedgrapheneoxidereinforcedpolylacticacidpolyethyleneglycolnanocompositespreparationcharacterizationandapplicationsinelectromagneticinterferenceshielding AT zaidmohdhafizmohd chemicallyreducedgrapheneoxidereinforcedpolylacticacidpolyethyleneglycolnanocompositespreparationcharacterizationandapplicationsinelectromagneticinterferenceshielding AT raadhaiderk chemicallyreducedgrapheneoxidereinforcedpolylacticacidpolyethyleneglycolnanocompositespreparationcharacterizationandapplicationsinelectromagneticinterferenceshielding AT aliyuumarsaad chemicallyreducedgrapheneoxidereinforcedpolylacticacidpolyethyleneglycolnanocompositespreparationcharacterizationandapplicationsinelectromagneticinterferenceshielding |