Cargando…

Chemically Reduced Graphene Oxide-Reinforced Poly(Lactic Acid)/Poly(Ethylene Glycol) Nanocomposites: Preparation, Characterization, and Applications in Electromagnetic Interference Shielding

In this study, a nanocomposite of reduced graphene oxide (RGO) nanofiller-reinforcement poly(lactic acid) (PLA)/poly(ethylene glycol) (PEG) matrix was prepared via the melt blending method. The flexibility of PLA was improved by blending the polymer with a PEG plasticizer as a second polymer. To enh...

Descripción completa

Detalles Bibliográficos
Autores principales: Ahmad, Ahmad Fahad, Aziz, Sidek Ab, Abbas, Zulkifly, Obaiys, Suzan Jabbar, Matori, Khamirul Amin, Zaid, Mohd Hafiz Mohd, Raad, Haider K., Aliyu, Umar Sa’ad
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6523337/
https://www.ncbi.nlm.nih.gov/pubmed/30978935
http://dx.doi.org/10.3390/polym11040661
_version_ 1783419310996193280
author Ahmad, Ahmad Fahad
Aziz, Sidek Ab
Abbas, Zulkifly
Obaiys, Suzan Jabbar
Matori, Khamirul Amin
Zaid, Mohd Hafiz Mohd
Raad, Haider K.
Aliyu, Umar Sa’ad
author_facet Ahmad, Ahmad Fahad
Aziz, Sidek Ab
Abbas, Zulkifly
Obaiys, Suzan Jabbar
Matori, Khamirul Amin
Zaid, Mohd Hafiz Mohd
Raad, Haider K.
Aliyu, Umar Sa’ad
author_sort Ahmad, Ahmad Fahad
collection PubMed
description In this study, a nanocomposite of reduced graphene oxide (RGO) nanofiller-reinforcement poly(lactic acid) (PLA)/poly(ethylene glycol) (PEG) matrix was prepared via the melt blending method. The flexibility of PLA was improved by blending the polymer with a PEG plasticizer as a second polymer. To enhance the electromagnetic interference shielding properties of the nanocomposite, different RGO wt % were combined with the PLA/PEG blend. Using Fourier-transform infrared (FT-IR) spectroscopy, field emission scanning electron microscopy (FE-SEM) and X-ray diffraction, the structural, microstructure, and morphological properties of the polymer and the RGO/PLA/PEG nanocomposites were examined. These studies showed that the RGO addition did not considerably affect the crystallinity of the resulting nanomaterials. Thermal analysis (TGA) reveals that the addition of RGO highly improved the thermal stability of PLA/PEG nanocomposites. The dielectric properties and electromagnetic interference shielding effectiveness of the synthesized nanocomposites were calculated and showed a higher SE total value than the target value (20 dB). On the other hand, the results showed an increased power loss by increasing the frequency and conversely decreased with an increased percentage of filler.
format Online
Article
Text
id pubmed-6523337
institution National Center for Biotechnology Information
language English
publishDate 2019
publisher MDPI
record_format MEDLINE/PubMed
spelling pubmed-65233372019-06-03 Chemically Reduced Graphene Oxide-Reinforced Poly(Lactic Acid)/Poly(Ethylene Glycol) Nanocomposites: Preparation, Characterization, and Applications in Electromagnetic Interference Shielding Ahmad, Ahmad Fahad Aziz, Sidek Ab Abbas, Zulkifly Obaiys, Suzan Jabbar Matori, Khamirul Amin Zaid, Mohd Hafiz Mohd Raad, Haider K. Aliyu, Umar Sa’ad Polymers (Basel) Article In this study, a nanocomposite of reduced graphene oxide (RGO) nanofiller-reinforcement poly(lactic acid) (PLA)/poly(ethylene glycol) (PEG) matrix was prepared via the melt blending method. The flexibility of PLA was improved by blending the polymer with a PEG plasticizer as a second polymer. To enhance the electromagnetic interference shielding properties of the nanocomposite, different RGO wt % were combined with the PLA/PEG blend. Using Fourier-transform infrared (FT-IR) spectroscopy, field emission scanning electron microscopy (FE-SEM) and X-ray diffraction, the structural, microstructure, and morphological properties of the polymer and the RGO/PLA/PEG nanocomposites were examined. These studies showed that the RGO addition did not considerably affect the crystallinity of the resulting nanomaterials. Thermal analysis (TGA) reveals that the addition of RGO highly improved the thermal stability of PLA/PEG nanocomposites. The dielectric properties and electromagnetic interference shielding effectiveness of the synthesized nanocomposites were calculated and showed a higher SE total value than the target value (20 dB). On the other hand, the results showed an increased power loss by increasing the frequency and conversely decreased with an increased percentage of filler. MDPI 2019-04-11 /pmc/articles/PMC6523337/ /pubmed/30978935 http://dx.doi.org/10.3390/polym11040661 Text en © 2019 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Ahmad, Ahmad Fahad
Aziz, Sidek Ab
Abbas, Zulkifly
Obaiys, Suzan Jabbar
Matori, Khamirul Amin
Zaid, Mohd Hafiz Mohd
Raad, Haider K.
Aliyu, Umar Sa’ad
Chemically Reduced Graphene Oxide-Reinforced Poly(Lactic Acid)/Poly(Ethylene Glycol) Nanocomposites: Preparation, Characterization, and Applications in Electromagnetic Interference Shielding
title Chemically Reduced Graphene Oxide-Reinforced Poly(Lactic Acid)/Poly(Ethylene Glycol) Nanocomposites: Preparation, Characterization, and Applications in Electromagnetic Interference Shielding
title_full Chemically Reduced Graphene Oxide-Reinforced Poly(Lactic Acid)/Poly(Ethylene Glycol) Nanocomposites: Preparation, Characterization, and Applications in Electromagnetic Interference Shielding
title_fullStr Chemically Reduced Graphene Oxide-Reinforced Poly(Lactic Acid)/Poly(Ethylene Glycol) Nanocomposites: Preparation, Characterization, and Applications in Electromagnetic Interference Shielding
title_full_unstemmed Chemically Reduced Graphene Oxide-Reinforced Poly(Lactic Acid)/Poly(Ethylene Glycol) Nanocomposites: Preparation, Characterization, and Applications in Electromagnetic Interference Shielding
title_short Chemically Reduced Graphene Oxide-Reinforced Poly(Lactic Acid)/Poly(Ethylene Glycol) Nanocomposites: Preparation, Characterization, and Applications in Electromagnetic Interference Shielding
title_sort chemically reduced graphene oxide-reinforced poly(lactic acid)/poly(ethylene glycol) nanocomposites: preparation, characterization, and applications in electromagnetic interference shielding
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6523337/
https://www.ncbi.nlm.nih.gov/pubmed/30978935
http://dx.doi.org/10.3390/polym11040661
work_keys_str_mv AT ahmadahmadfahad chemicallyreducedgrapheneoxidereinforcedpolylacticacidpolyethyleneglycolnanocompositespreparationcharacterizationandapplicationsinelectromagneticinterferenceshielding
AT azizsidekab chemicallyreducedgrapheneoxidereinforcedpolylacticacidpolyethyleneglycolnanocompositespreparationcharacterizationandapplicationsinelectromagneticinterferenceshielding
AT abbaszulkifly chemicallyreducedgrapheneoxidereinforcedpolylacticacidpolyethyleneglycolnanocompositespreparationcharacterizationandapplicationsinelectromagneticinterferenceshielding
AT obaiyssuzanjabbar chemicallyreducedgrapheneoxidereinforcedpolylacticacidpolyethyleneglycolnanocompositespreparationcharacterizationandapplicationsinelectromagneticinterferenceshielding
AT matorikhamirulamin chemicallyreducedgrapheneoxidereinforcedpolylacticacidpolyethyleneglycolnanocompositespreparationcharacterizationandapplicationsinelectromagneticinterferenceshielding
AT zaidmohdhafizmohd chemicallyreducedgrapheneoxidereinforcedpolylacticacidpolyethyleneglycolnanocompositespreparationcharacterizationandapplicationsinelectromagneticinterferenceshielding
AT raadhaiderk chemicallyreducedgrapheneoxidereinforcedpolylacticacidpolyethyleneglycolnanocompositespreparationcharacterizationandapplicationsinelectromagneticinterferenceshielding
AT aliyuumarsaad chemicallyreducedgrapheneoxidereinforcedpolylacticacidpolyethyleneglycolnanocompositespreparationcharacterizationandapplicationsinelectromagneticinterferenceshielding